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Merck
CN

731439

Sigma-Aldrich

9,10-双[（三异丙基甲硅烷基）乙炔基]蒽

>99%

别名:

9,10-Bis{2-[tris(1-methylethyl)silyl]ethynyl}anthracene, TIPS-anthracene

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关于此项目

经验公式（希尔记法）:
C36H50Si2
化学文摘社编号:
862667-06-9
分子量:
538.95
MDL编号:
MFCD15530143
UNSPSC代码:
12352103
PubChem化学物质编号:
329764654
NACRES:
NA.23

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方案

>99%

表单

solid

mp

211-214 °C

λmax

1.8732 at 274 nm

吸附

0.25821 at 394 nm
0.61112 at 416 nm
0.84016 at 442 nm

荧光

λex 435 nm; λem 475 nm (concentration = 0.00002 mg/mL)

轨道能量

HOMO 5.6 eV (CV)
LUMO 2.9 eV (CV)

SMILES字符串

CC(C)[Si](C#Cc1c2ccccc2c(C#C[Si](C(C)C)(C(C)C)C(C)C)c3ccccc13)(C(C)C)C(C)C

InChI

1S/C36H50Si2/c1-25(2)37(26(3)4,27(5)6)23-21-35-31-17-13-15-19-33(31)36(34-20-16-14-18-32(34)35)22-24-38(28(7)8,29(9)10)30(11)12/h13-20,25-30H,1-12H3

InChI key

FEAZNDXDTUMTIL-UHFFFAOYSA-N

一般描述

9,10-Bis[(triisopropylsilyl)ethynyl]anthracene is a novel organic photocatalyst.

应用

The photocatalyst may be useful in the affording free radicals during polymerization via irradiated photoredox catalysis.

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKBD8851

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Organic photocatalyst for polymerization reactions: 9, 10-bis [(triisopropylsilyl) ethynyl] anthracene.
Tehfe, Mohamad-Ali, et al.
ACS Macro Letters, 198-203 null
Intermolecular Effects on the Hole States of Triisopropylsilylethynyl-Substituted Oligoacenes
Griffith, O. L.; Jones, A. G.; Anthony, J. E.; Lichtenberger, D. L.
The Journal of Physical Chemistry C, 114, 13838-13838 (2010)
Jong-Hwa Park et al.
Organic letters, 9(13), 2573-2576 (2007-06-05)
New soluble anthracene derivatives containing thiophene and phenylenevinylene derivatives were synthesized via well-known synthetic routes. TIPS derivatives were added at the 9,10-positions of anthracene for the solubility and crystallinity. Both of the molecules were found to be promising for high
Organic photocatalyst for polymerization reactions: 9, 10-bis [(triisopropylsilyl) ethynyl] anthracene.
Tehfe, Mohamad-Ali, et al.
ACS Macro Letters null

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