736635
Bis(tricyclohexylphosphine)palladium(0)
别名:
Pd(PCy3)2
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关于此项目
经验公式（希尔记法）:
C36H66P2Pd
化学文摘社编号:
分子量:
667.28
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352300
MDL number:
form
solid
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
mp
87-92 °C
storage temp.
2-8°C
SMILES string
[Pd].C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C4CCC(CC4)P(C5CCCCC5)C6CCCCC6
InChI
1S/2C18H33P.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h2*16-18H,1-15H2;
InChI key
JGBZTJWQMWZVNX-UHFFFAOYSA-N
Application
Bis(tricyclohexylphosphine)palladium(0) [Pd(PCy3)2] is a general palladium precatalyst that can be used to catalyze various reactions such as thioesterification of alkynes, alumination of unactivated arenes, direct arylation polycondensation and intramolecular alkane arylation adjacent to amides and sulfonamides.
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
Direct arylation polycondensation for synthesis of optoelectronic materials.
Kuwabara J.
Polymer Journal (2018)
Room temperature catalytic carbon?hydrogen bond alumination of unactivated arenes: mechanism and selectivity.
Hooper T, et al.
Chemical Science, 9, 5435-5440 (2018)
Palladium-catalyzed thioesterification of alkynes with O-methyl S-phenyl thiocarbonate.
Hua R, et al.
Journal of the American Chemical Society, 123(12), 2899-2900 (2001)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 736635-1G | 04061826724811 |
| 736635-250MG | 04061833555545 |