产品名称
3-丁炔酸, 95%
SMILES string
OC(=O)CC#C
InChI
1S/C4H4O2/c1-2-3-4(5)6/h1H,3H2,(H,5,6)
InChI key
KKAHGSQLSTUDAV-UHFFFAOYSA-N
assay
95%
form
powder
mp
70-80 °C
Quality Level
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Application
3-丁酸的一些应用是:
- 功能化 γ 的合成-丁酸内酯和四氢呋喃通过锥烯环化。
- 烯丙基酯与烯烃的 [2 + 2] 环加成反应的合成。
- 膦酰基催化合成高度功能化的香豆素。
- 通过 3-丁酸的自由基湿法合成各种有用的有机锡试剂。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Synergistic Diazo?OH Insertion/Conia?Ene Cascade Catalysis for the Stereoselective Synthesis of ??Butyrolactones and Tetrahydrofurans.
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Catalytic Enantioselective Allenoate?Alkene [2+ 2] Cycloadditions.
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Phosphine-catalyzed synthesis of highly functionalized coumarins.
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Organic Letters, 9(16), 3069-3072 (2007)
Zhipeng Li et al.
The Analyst, 145(12), 4239-4244 (2020-05-22)
The aim of this study was to overcome the reported shortcomings of the glutathione (GSH) detection of rhodamine-based fluorescent probes, such as poor selectivity to thiol groups and reversible unstable covalent binding with the thiol groups. Here, we have developed
Ionogels, new materials arising from the confinement of ionic liquids within silica-derived networks.
Neouze M A, et al.
Chemistry of Materials, 18(17), 3931-3936 (2006)
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