742236
[4-(三氟甲基)苯基](2,4,6-三甲基苯基)三氟甲磺酸碘鎓
≥98% (HPLC)
别名:
[4-(Trifluoromethyl)phenyl](2,4,6-trimethylphenyl)iodonium trifluoromethanesulfonate
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关于此项目
经验公式（希尔记法）:
C17H15F6IO3S
化学文摘社编号:
分子量:
540.26
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
20424731
Assay:
≥98% (HPLC)
Form:
solid
InChI
1S/C16H15F3I.CHF3O3S/c1-10-8-11(2)15(12(3)9-10)20-14-6-4-13(5-7-14)16(17,18)19;2-1(3,4)8(5,6)7/h4-9H,1-3H3;(H,5,6,7)/q+1;/p-1
SMILES string
CC1=CC(C)=C([I+]C2=CC=C(C=C2)C(F)(F)F)C(C)=C1.O=S([O-])(C(F)(F)F)=O
InChI key
XTTMIKRDUJQRGJ-UHFFFAOYSA-M
assay
≥98% (HPLC)
form
solid
composition
carbon, 36.8-38.7% CH
Application
[4-(Trifluoromethyl)phenyl](2,4,6-trimethylphenyl)iodonium triflate can be used as:
- A Lewis acid catalyst in the metal-free cationic polymerization of styrene and alkyl vinyl ether derivatives.
- An arylating agent in the arylalkynylation of alkenes.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Copper-catalyzed enantioselective arylalkynylation of alkenes
Lei G, et al.
Chemical Science, 11(6), 1623-1628 (2020)
Metal-Free Living Cationic Polymerization Using Diaryliodonium Salts as Organic Lewis Acid Catalysts
Haraguchi R, et al.
Macromolecules, 53, 4185?4192-4185?4192 (2020)
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