方案
≥98% (HPLC)
表单
powder
旋光性
[α]/D +75±3°, c = 1 in dichloromethane
杂质
≤2.0% water
SMILES字符串
[I-].CC(C)(C)[C@@H](c1cccc2ccccc12)n3cc[n+](c3)[C@@H](c4cccc5ccccc45)C(C)(C)C
InChI
1S/C33H37N2.HI/c1-32(2,3)30(28-19-11-15-24-13-7-9-17-26(24)28)34-21-22-35(23-34)31(33(4,5)6)29-20-12-16-25-14-8-10-18-27(25)29;/h7-23,30-31H,1-6H3;1H/q+1;/p-1/t30-,31+;
InChI key
DZXSGMCSEFOYEQ-USHPRDJASA-M
应用
Carbene ligand precursor
包装
Bottomless glass bottle. Contents are inside inserted fused cone.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
Banerjee, D.; et al.
Organometallics, 31, 709-709 (2012)
Masafumi Nakanishi et al.
Chimia, 66(4), 241-243 (2012-05-23)
New sterically hindered chiral N-heterocyclic carbene (NHC) ligands were used in palladium catalysis to bring about a highly enantioselective C(sp(3))-H activation on the methylene site of a cycloalkane moiety. The intramolecular coupling reaction of a prochiral N-aryl-N-cycloalkyl methyl carbamate required
Fused indolines by palladium-catalyzed asymmetric C-C coupling involving an unactivated methylene group.
Masafumi Nakanishi et al.
Angewandte Chemie (International ed. in English), 50(32), 7438-7441 (2011-07-05)
Nakanishi, M.; et al.
Angewandte Chemie (International Edition in English), 50, 9775-9775 (2011)
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