743674
1,3-Bis(2,7-diisopropylnaphthalen-1-yl)imidazolinium tetrafluoroborate
≥95% (HPLC)
别名:
2,7-SIPrNap·HBF4
方案
≥95% (HPLC)
表单
powder
反应适用性
reagent type: catalyst
SMILES字符串
F[B-](F)(F)F.CC(C)c1ccc2ccc(C(C)C)c(N3CC[N+](=C3)c4c(ccc5ccc(cc45)C(C)C)C(C)C)c2c1
InChI
1S/C35H43N2.BF4/c1-22(2)28-11-9-26-13-15-30(24(5)6)34(32(26)19-28)36-17-18-37(21-36)35-31(25(7)8)16-14-27-10-12-29(23(3)4)20-33(27)35;2-1(3,4)5/h9-16,19-25H,17-18H2,1-8H3;/q+1;-1
InChI key
JHTIXBSEIAAUNV-UHFFFAOYSA-N
一般描述
Mixture of anti and syn isomers in variable ratios. Generally anti as major component.
应用
Carbene ligand precursor
包装
Bottomless glass bottle. Contents are inside inserted fused cone.
Vieille-Petit, L.; et al.
Chemical Communications (Cambridge, England), 3783-3783 (2009)
Xinjun Luan et al.
Journal of the American Chemical Society, 130(21), 6848-6858 (2008-05-01)
A new class of easily accessible and stable imidazolin-2-ylidenes has been synthesized where the side chains are comprised of substituted naphthyl units. Introduction of the naphthyl groups generates C 2 -symmetric ( rac) and C s- symmetric ( meso) atropisomers
Vieille-Petit, L.; et al.
European Journal of Inorganic Chemistry, 13, 1861-1861 (2009)
Michele Gatti et al.
Journal of the American Chemical Society, 131(27), 9498-9499 (2009-06-19)
Two saturated N-heterocyclic carbene ligands with substituted naphthyl side chains were used for the preparation of Blechert-type ruthenium metathesis precatalysts. The resulting conformers of the complexes were separated and unambiguously assigned by X-ray diffraction studies. All new complexes were compared
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