745103
(2R)-N-[(1R)-1-(Hydroxydiphenylmethyl)-3-methylbutyl]-2-pyrrolidinecarboxamide
≥98.0% (HPLC)
别名:
(R)-N-((R)-1-Hydroxy-4-methyl-1,1-diphenylpentan-2-yl)pyrrolidine-2-carboxamide, N-[(1R)-1-(Hydroxydiphenylmethyl)-3-methylbutyl]-D-prolinamide
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关于此项目
经验公式（希尔记法）:
C23H30N2O2
CAS Number:
分子量:
366.50
Beilstein:
19106160
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
方案
≥98.0% (HPLC)
表单
powder
旋光性
[α]/D 50.9±3°, c = 1 in chloroform
mp
194 °C±3 °C
官能团
amide
hydroxyl
phenyl
SMILES字符串
CC(C)C[C@@H](NC(=O)[C@H]1CCCN1)C(O)(c2ccccc2)c3ccccc3
InChI
1S/C23H30N2O2/c1-17(2)16-21(25-22(26)20-14-9-15-24-20)23(27,18-10-5-3-6-11-18)19-12-7-4-8-13-19/h3-8,10-13,17,20-21,24,27H,9,14-16H2,1-2H3,(H,25,26)/t20-,21-/m1/s1
InChI key
PWBULUUPVDXEQS-NHCUHLMSSA-N
包装
Bottomless glass bottle. Contents are inside inserted fused cone.
分析说明
C-NMR and H-NMR conforms to structure
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
Direction of Kinetically versus Thermodynamically Controlled Organocatalysis and Its Application in Chemoenzymatic Synthesis
Rulli, G., et al.
Angewandte Chemie (International Edition in English), 50, 1-5 (2011)
Monika Raj et al.
Organic letters, 8(18), 4097-4099 (2006-08-25)
We have demonstrated that a new class of l-proline-based organic compounds catalyzed the direct aldol reaction between aldehydes and acetone to provide beta-hydroxy ketones in good yields. The reaction is efficient, and 5-10 mol % of the catalyst and excellent
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