745480
Zinc isopropylsulfinate
95%
别名:
Baran Isopropylation Reagent, Baran IPS Reagent, Bis((isopropylsulfinyl)oxy)zinc, IPS
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关于此项目
经验公式（希尔记法）:
C6H14O4S2Zn
化学文摘社编号:
分子量:
279.69
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
MDL number:
Assay:
95%
Form:
solid
InChI
1S/2C3H8O2S.Zn/c2*1-3(2)6(4)5;/h2*3H,1-2H3,(H,4,5);/q;;+2/p-2
SMILES string
CC(C)S(=O)O[Zn]OS(=O)C(C)C
InChI key
PEEMMWYYSHSBTQ-UHFFFAOYSA-L
assay
95%
form
solid
reaction suitability
reaction type: Allylation, reaction type: C-C Bond Formation, reagent type: catalyst
reaction type: C-H Activation, reagent type: diversification reagent
mp
161-166 °C
functional group
sulfinic acid
Quality Level
Application
Zinc isopropylsulfinate (IPS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.
Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles
Learn More at the Professor and Product Portal of Professor Phil S. Baran.
Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles
Learn More at the Professor and Product Portal of Professor Phil S. Baran.
Preparation Note
may contain up to 1 mole eq ZnCl2
Other Notes
Frequently Asked Questions are available for this Product.
Previously sold under product number L511161
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Bonnie Bailet et al.
The Science of the total environment, 745, 140948-140948 (2020-08-01)
Ecological assessment of lakes and rivers using benthic diatom assemblages currently requires considerable taxonomic expertise to identify species using light microscopy. This traditional approach is also time-consuming. Diatom metabarcoding is a promising alternative and there is increasing interest in using
Meiqi Niu et al.
eLife, 9 (2020-07-03)
The intraparietal sulcus (IPS) is structurally and functionally heterogeneous. We performed a quantitative cyto-/myelo- and receptor architectonical analysis to provide a multimodal map of the macaque IPS. We identified 17 cortical areas, including novel areas PEipe, PEipi (external and internal
Thapanee Srichumpong et al.
Dental materials journal, 38(3), 378-387 (2019-03-15)
The mica-based glass-ceramics were prepared in the SiO2-Al2O3-MgO-MgF2-SrCO3-CaCO3-CaF2-P2O5 glass system. There were four mica-based glass-ceramics produced in this study according to the pigment added (CeO2 or Pr-ZrSiO4/Fe-ZrSiO4) and crystallization time (5-35 min). Four dental glass-ceramics, which were leucite-based, lithium disilicate-based
Yan-Jie Chunyu et al.
Journal of agricultural and food chemistry, 67(31), 8476-8484 (2019-07-13)
Cicada flowers, which are edible and medicinal mushrooms, are the fruiting bodies of Isaria cicadae, a fungus that is parasitic on the larvae of cicada pupae. We hypothesize that host factors might possess stimulatory activity on metabolite synthesis in Isaria
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Zerumbone has shown great potential in various pathophysiological models of diseases, particularly in neuropathic pain conditions. Further understanding the mechanisms of action is important to develop zerumbone as a potential anti-nociceptive agent. Numerous receptors and pathways function to inhibit and
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Rapidly diversify (hetero)aromatic scaffolds for chemical industry needs amid resource and time constraints, ensuring efficiency.
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