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Merck
CN

745480

Zinc isopropylsulfinate

95%

别名:

Baran Isopropylation Reagent, Baran IPS Reagent, Bis((isopropylsulfinyl)oxy)zinc, IPS

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关于此项目

经验公式（希尔记法）:
C6H14O4S2Zn
化学文摘社编号:
1416821-55-0
分子量:
279.69
MDL编号:
MFCD24386390
UNSPSC代码:
12352001
PubChem化学物质编号:
329764984
NACRES:
NA.22

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方案

95%

表单

solid

反应适用性

reaction type: Allylation
reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation
reagent type: diversification reagent

mp

161-166 °C

官能团

sulfinic acid

SMILES字符串

CC(C)S(=O)O[Zn]OS(=O)C(C)C

InChI

1S/2C3H8O2S.Zn/c2*1-3(2)6(4)5;/h2*3H,1-2H3,(H,4,5);/q;;+2/p-2

InChI key

PEEMMWYYSHSBTQ-UHFFFAOYSA-L

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相关类别

应用

Zinc isopropylsulfinate (IPS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.


Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

制备说明

may contain up to 1 mole eq ZnCl2

其他说明

Frequently Asked Questions are available for this Product.
Previously sold under product number L511161

警示用语：

Danger

危险声明

H314,H335,H410

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

靶器官

Respiratory system

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCN1076
MKCJ2637
MKCD0333
MKCB0914V
MKBX5822V

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Rie Poulsen et al.
Trials, 18(1), 578-578 (2017-12-05)
Depression and anxiety are among the largest contributors to the global burden of disease and have negative effects on both the individual and society. Depression and anxiety are very likely to influence the individual's work ability, and up to 40%
Chun You et al.
Biotechnology and bioengineering, 114(8), 1855-1864 (2017-04-15)
Myo-Inositol (vitamin B8) is widely used in the drug, cosmetic, and food & feed industries. Here, we present an in vitro non-fermentative enzymatic pathway that converts starch to inositol in one vessel. This in vitro pathway is comprised of four
Elisa Zamboni et al.
eLife, 9 (2020-11-11)
Adapting to the environment statistics by reducing brain responses to repetitive sensory information is key for efficient information processing. Yet, the fine-scale computations that support this adaptive processing in the human brain remain largely unknown. Here, we capitalise on the
Q van Geest et al.
NeuroImage. Clinical, 19, 507-515 (2018-07-10)
To explore the added value of dynamic functional connectivity (dFC) of the default mode network (DMN) during resting-state (RS), during an information processing speed (IPS) task, and the within-subject difference between these conditions, on top of conventional brain measures in
Meiqi Niu et al.
eLife, 9 (2020-07-03)
The intraparietal sulcus (IPS) is structurally and functionally heterogeneous. We performed a quantitative cyto-/myelo- and receptor architectonical analysis to provide a multimodal map of the macaque IPS. We identified 17 cortical areas, including novel areas PEipe, PEipi (external and internal
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Baran Diversinates™

Rapidly diversify (hetero)aromatic scaffolds for chemical industry needs amid resource and time constraints, ensuring efficiency.

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