745499
Zinc trifluoroethanesulfinate
别名:
Baran TFES Reagent, Baran Trifluoroethylation Reagent, Bis(((2,2,2-trifluoroethyl)sulfinyl)oxy)zinc, TFES
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关于此项目
经验公式（希尔记法）:
C4H4F6O4S2Zn
化学文摘社编号:
分子量:
359.58
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
表单
solid
反应适用性
reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation
mp
114-120 °C
官能团
fluoro
sulfinic acid
SMILES字符串
O=S(O[Zn]OS(CC(F)(F)F)=O)CC(F)(F)F
InChI
1S/2C2H3F3O2S.Zn/c2*3-2(4,5)1-8(6)7;/h2*1H2,(H,6,7);/q;;+2/p-2
InChI key
PUGHSSOALZPRJD-UHFFFAOYSA-L
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一般描述
Zinc trifluoroethanesulfinate (TFES) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.
Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles
Learn More at the Professor and Product Portal of Professor Phil S. Baran.
Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles
Learn More at the Professor and Product Portal of Professor Phil S. Baran.
其他说明
Frequently Asked Questions are available for this Product.
Previously sold under product number L511234
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Fionn O'Hara et al.
Journal of the American Chemical Society, 135(32), 12122-12134 (2013-07-19)
Radical addition processes can be ideally suited for the direct functionalization of heteroaromatic bases, yet these processes are only sparsely used due to the perception of poor or unreliable control of regiochemistry. A systematic investigation of factors affecting the regiochemistry
Yuta Fujiwara et al.
Nature, 492(7427), 95-99 (2012-12-04)
Nitrogen-rich heterocyclic compounds have had a profound effect on human health because these chemical motifs are found in a large number of drugs used to combat a broad range of diseases and pathophysiological conditions. Advances in transition-metal-mediated cross-coupling have simplified
商品
Rapidly diversify (hetero)aromatic scaffolds for chemical industry needs amid resource and time constraints, ensuring efficiency.
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