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745901

PBTTPD

别名:

Poly[[5-(2-ethylhexyl)-5,6-dihydro-4,6-dioxo-4H-thieno[3,4-c]pyrrole-1,3-diyl](4,4′-didodecyl[2,2′-bithiophene]-5,5′-diyl)]

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关于此项目

线性分子式:
(C46H69NO2S3)n
化学文摘社编号:
1240372-42-2
NACRES:
NA.23
UNSPSC Code:
12352103
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description

Band gap: 1.82 eV

form

solid

mol wt

average Mn 3,500-20,000 g/mol

λmax

572 nm (thin film)

orbital energy

HOMO -5.56 eV , LUMO -3.1 eV 

PDI

1.2‑2.5

General description

PBTTPD is a donor-acceptor based high crystalline conducting polymer. It has thieno[3,4-c]pyrrole-4,6-dione (TPD), which acts as the electron-withdrawing group. Bi(dodecyl)thiophene based donor groups facilitate the polymeric unit with crystallinity and low HOMO energy levels. It shows good hole mobility and open circuit voltage (VOC).
HOMO: -5.56 eV
LUMO: -3.10 eV
UV absorption: λmax = 572 nm;Eg = 1.82 eV
Solubility: This polymer can be dissolved easily in hot chloroform;hot chlorobenzene;hot dichlorobenzene

Application

PBTTPD is majorly used as a conjugating polymer in the fabrication of organic solar cells (OSCs) and organic photovoltaic cells (OPVs). It has a power conversion efficiency (PCE) of 7.3% and a VOC of 0.92V.
  • High-Efficiency Organic Solar Cells (OPVs)
  • Power conversion efficiency (PCE): 7.3%
  • Open circuit voltage (Voc): 0.92 V
  • Short circuit current density (Jsc): 13.1 mA/cm2
  • Fill factor (FF): 0.61

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKBR9502V

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货号GTIN
745901-100MG04061832939018