746061
二氟甲基 (2-吡啶基)砜
97% (HPLC)
别名:
2-[(Difluoromethyl)sulfonyl]pyridine, Hu Reagent, 2-(Difluoromethylsulfonyl)pyridine, 2-PySO2CF2H
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关于此项目
经验公式（希尔记法）:
C6H5F2NO2S
化学文摘社编号:
分子量:
193.17
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
20317604
Assay:
97% (HPLC)
Form:
solid
Quality Segment
assay
97% (HPLC)
form
solid
mp
44-49 °C
functional group
fluoro, sulfone
SMILES string
O=S(C1=CC=CC=N1)(C(F)F)=O
InChI
1S/C6H5F2NO2S/c7-6(8)12(10,11)5-3-1-2-4-9-5/h1-4,6H
InChI key
YRQNSTAWTLXCEZ-UHFFFAOYSA-N
General description
Difluoromethyl 2-pyridyl sulfone (2-PySO2CF2H) is a reagent used in the gem-difluoroolefination of aldehydes and ketones. It is also used as a reagent in the nucleophilic difluoro(sulfonato)methylation of alcohols, N-sulfinyl imines, and halides.
Application
Reagent is used in the olefination of ketones and aldehydes to form gem-difluoro olefins under basic conditions. Product is also used as a crucial intermediate toward making 1,1-difluorinated alkyl chains for the alkylation of heterocycles.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Irrit. 2
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable