748196
(1R,2R)-2-氨基-1-苯基丙基二苯基膦
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关于此项目
经验公式（希尔记法）:
C21H22NP
化学文摘社编号:
分子量:
319.38
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
MDL number:
InChI
1S/C21H22NP/c1-17(22)21(18-11-5-2-6-12-18)23(19-13-7-3-8-14-19)20-15-9-4-10-16-20/h2-17,21H,22H2,1H3/t17-,21+/m1/s1
SMILES string
C[C@@H](N)[C@H](P(c1ccccc1)c2ccccc2)c3ccccc3
InChI key
JWZAIGGNEGTDMG-UTKZUKDTSA-N
form
solid
optical activity
[α]/D -138.0°, c = 0.5% in chloroform
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
mp
105-109 °C
functional group
phosphine
storage temp.
20-25°C
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Chemoselective hydrogenation of imides catalyzed by Cp*Ru(PN) complexes and its application to the asymmetric synthesis of paroxetine.
Masato Ito et al.
Journal of the American Chemical Society, 129(2), 290-291 (2007-01-11)
Masato Ito et al.
Angewandte Chemie (International ed. in English), 48(7), 1324-1327 (2009-01-09)
Awakening of the Cp one: The bifunctional complex 1 facilitates the interaction with substrates bearing less electrophilic carbon atoms than ketones, epoxides, and imides. The title reaction was applicable to the reduction of Evans' asymmetric alkylation products to the chiral
Isaac J Krauss et al.
Organic letters, 5(18), 3201-3203 (2003-08-29)
[reaction: see text] A new ligand for Cu-catalyzed enantioselective additions of dialkylzincs to cyclic enones has been developed. In addition to providing good to excellent enantioselectivities with a range of cyclic enones and dialkylzincs, the ligand has several notworthy features:
D. Amoroso, T.W. Graham et al.
Aldrichimica Acta, 41, 1-1 (2008)
A Saitoh et al.
The Journal of organic chemistry, 65(14), 4227-4240 (2000-07-13)
A new class of chiral amidine-phosphine hybrid ligands 7a,b, which are readily accessible from the corresponding alpha-amino acids, were developed. A versatility for construction of new ligands is desirable, by which a variety of reactions and substrates become applicable. Indeed
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