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749125

Cobalt(II) oxo pivalate

Name: Cobalt(II) oxo pivalate
Brand: ALDRICH

别名:

Basic cobalt(II) pivalate, Cobalt, hexakis[μ-(2,2-dimethylpropanoato-κO:κO′)]hexakis[μ₃-(2,2-dimethylpropanoato-κO:κO:κO′)]di-μ₄-oxoocta-, Tetrameric Co cluster

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关于此项目

经验公式（希尔记法）:

C₆₀H₁₀₈Co₈O₂₆

化学文摘社编号:

301663-94-5

分子量:

1716.95

NACRES:

NA.23

PubChem Substance ID:

329765968

UNSPSC Code:

26111700

MDL number:

MFCD22200509

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属性

Quality Level

100

form

powder

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Enabling,

SMILES string

CC(C)(C)C(=O)O[Co-]1O[Co-](O\C(=[O+]/[Co-](OC(=O)C(C)(C)C)O\C(=[O+]/[Co-](OC(=O)C(C)(C)C)OC(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C)[O+]=C(O[Co-]2O[Co-](O\C(=[O+]\1)C(C)(C)C)\[O+]=C(\O[Co-](OC(=O)C(C)(C)C)\[O+]=C(\O[Co]OC(=[O+]2)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C

InChI

1S/12C5H10O2.8Co.2O/c12*1-5(2,3)4(6)7;;;;;;;;;;/h12*1-3H3,(H,6,7);;;;;;;;;;/q;;;;;;;;;;;;4*+1;4*+2;;/p-12

InChI key

PBKALLJUIAKYSI-UHFFFAOYSA-B

说明

General description

Cobalt(II) oxo pivalate is a dinuclear complex that is typically formed by the direct reaction of cobalt carbonate with pivalic acid, followed by crystallization from MeCN. Its structure has two Co(II) sites bridged by two 2,11-carboxylates (Harris notation) and an oxygen atom.

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Application

Synthesis of trinuclear complex [Co₃(Piv)₂L¹₂L²₂] by reacting cobalt(II)pivalate with spin labeled Schiff base has been reported in a study.

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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分析证书(COA)

Lot/Batch Number

MKBJ4129V

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Synthetic and structural studies of cobalt-pivalate complexes

Aromi G, et al.

Chemistry?A European Journal , 9(20), 5142-5161 (2003)

Redox-Induced Change in the Ligand Coordination Mode.

Ovcharenko V, et al.

Inorganic Chemistry, 53(19), 10033-10035 (2014)

Large pores generated by the combination of different inorganic units in a zinc hydroxide ethynylene diisophthalate MOF.

Steffen Hausdorf et al.

Dalton transactions (Cambridge, England : 2003), 7(7), 1107-1113 (2009-03-27)

An ethynylene diisophthalic acid linker molecule was synthesized and used to form a zinc carboxylate-based metal organic framework (MOF) with very large pores and unit cell volume resulting from the unusual combination of structurally different inorganic units forming the secondary

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全球贸易项目编号

货号	GTIN
749125-500MG	04061833241202