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Merck
CN

749125

Cobalt(II) oxo pivalate

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别名:

Basic cobalt(II) pivalate, Cobalt, hexakis[μ-(2,2-dimethylpropanoato-κO:κO′)]hexakis[μ3-(2,2-dimethylpropanoato-κO:κO:κO′)]di-μ4-oxoocta-, Tetrameric Co cluster

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关于此项目

经验公式（希尔记法）:
C60H108Co8O26
化学文摘社编号:
301663-94-5
分子量:
1716.95
NACRES:
NA.23
PubChem Substance ID:
329765968
UNSPSC Code:
26111700
MDL number:
MFCD22200509

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Quality Level

100

InChI

1S/12C5H10O2.8Co.2O/c12*1-5(2,3)4(6)7;;;;;;;;;;/h12*1-3H3,(H,6,7);;;;;;;;;;/q;;;;;;;;;;;;4*+1;4*+2;;/p-12

SMILES string

CC(C)(C)C(=O)O[Co-]1O[Co-](O\C(=[O+]/[Co-](OC(=O)C(C)(C)C)O\C(=[O+]/[Co-](OC(=O)C(C)(C)C)OC(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C)[O+]=C(O[Co-]2O[Co-](O\C(=[O+]\1)C(C)(C)C)\[O+]=C(\O[Co-](OC(=O)C(C)(C)C)\[O+]=C(\O[Co]OC(=[O+]2)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C

InChI key

PBKALLJUIAKYSI-UHFFFAOYSA-B

form

powder

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Design for Energy Efficiency
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greener alternative category

Enabling,

相关类别

Application

Synthesis of trinuclear complex [Co3(Piv)2L12L22] by reacting cobalt(II)pivalate with spin labeled Schiff base has been reported in a study.

General description

Cobalt(II) oxo pivalate is a dinuclear complex that is typically formed by the direct reaction of cobalt carbonate with pivalic acid, followed by crystallization from MeCN. Its structure has two Co(II) sites bridged by two 2,11-carboxylates (Harris notation) and an oxygen atom.
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存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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分析证书(COA)

Lot/Batch Number
MKBJ4129V

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Redox-Induced Change in the Ligand Coordination Mode.
Ovcharenko V, et al.
Inorganic Chemistry, 53(19), 10033-10035 (2014)
Synthetic and structural studies of cobalt-pivalate complexes
Aromi G, et al.
Chemistry?A European Journal , 9(20), 5142-5161 (2003)
Steffen Hausdorf et al.
The journal of physical chemistry. A, 112(33), 7567-7576 (2008-07-26)
The contributions of terephthalic acid and Zn(2+)-coordinated water in N,N-diethylformamide (DEF) to the overall proton activity in the synthesis of MOF-5 (Zn4O(BDC)3, BDC = 1,4-benzenedicarboxylate) were quantitatively determined by combined electrochemical and UV-vis spectroscopic measurements. Structural transformations of zinc carboxylate-based
Steffen Hausdorf et al.
Dalton transactions (Cambridge, England : 2003), 7(7), 1107-1113 (2009-03-27)
An ethynylene diisophthalic acid linker molecule was synthesized and used to form a zinc carboxylate-based metal organic framework (MOF) with very large pores and unit cell volume resulting from the unusual combination of structurally different inorganic units forming the secondary
Steffen Hausdorf et al.
Journal of the American Chemical Society, 132(32), 10978-10981 (2010-08-12)
A simple two-component procedure was developed to synthesize not only classical zinc-based IRMOFs represented by MOF-5 but also the cobalt and beryllium homologues of this most prominent MOF. The procedure is the first manifestation of mirroring the IRMOF series with

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