750263
Potassium 1-(phenylsulfonyl)-1H-indole-3-trifluoroborate
95%
别名:
Potassium 1-(phenylsulfonyl)-3-indoletrifluoroborate, Potassium 1-(phenylsulfonyl)-3-indolyltrifluoroborate
方案
95%
表单
solid
mp
283-290 °C
SMILES字符串
[K+].F[B-](F)(F)c1cn(c2ccccc12)S(=O)(=O)c3ccccc3
InChI
1S/C14H10BF3NO2S.K/c16-15(17,18)13-10-19(14-9-5-4-8-12(13)14)22(20,21)11-6-2-1-3-7-11;/h1-10H;/q-1;+1
InChI key
XLOGEONPZAROPE-UHFFFAOYSA-N
应用
Potassium 1-(phenylsulfonyl)-1H-indole-3-trifluoroborate can be used as a reactant in:
- The palladium-catalyzed Suzuki-Miyaura α-arylation reaction.
- The nucleophilic addition reactions.
- The preparation of indole substituted borazaronaphthalene.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
此项目有
Method for Accessing Nitrogen-Containing, B-Heteroaryl-Substituted 2, 1-Borazaronaphthalenes
Davies GHM, et al.
The Journal of Organic Chemistry, 82(1), 549-555 (2017)
Oxyallyl Cation Capture via Electrophilic Deborylation of Organoboronates: Access to α , α `-Substituted Cyclic Ketones
Nguyen TN, et al.
Organic Letters, 21(19), 7837-7840 (2019)
Gary A Molander et al.
The Journal of organic chemistry, 78(8), 4123-4131 (2013-04-11)
A method has been developed for the Pd-catalyzed synthesis of α-(hetero)aryl esters and amides through a Suzuki-Miyaura cross-coupling reaction. This method avoids the use of strong base, does not necessitate inert or low temperature formation of reagents, and does not
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