754706
8-Isopropylquinoline N-oxide
97%
别名:
8-Isopropylquinoline 1-oxide
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关于此项目
经验公式（希尔记法）:
C12H13NO
化学文摘社编号:
分子量:
187.24
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Assay:
97%
Form:
liquid
InChI
1S/C12H13NO/c1-9(2)11-7-3-5-10-6-4-8-13(14)12(10)11/h3-9H,1-2H3
SMILES string
CC(C)c1cccc2ccc[n+]([O-])c12
InChI key
LYLSTLGFFOQSKE-UHFFFAOYSA-N
assay
97%
form
liquid
refractive index
n20/D 1.644
density
1.134 g/mL at 25 °C
storage temp.
2-8°C
Application
8-Isopropylquinoline N-oxide can be used as a reagent:
- In the oxidative cyclization of diynes in the presence of gold catalyst.
- For the preparation of pyrrolo[3,4-c]quinolin-1-ones by asymmetric alkyne oxidation of chiral N-propargyl ynamides in the presence of a copper catalyst.
- In the synthesis of 8-(1-methylethyl)-2-[(4-methylphenyl)sulfonyl]- quinoline by deoxygenative and selective sulfonylation with sodium p-toluenesulfinate using iodine/TBHP as a catalyst.
存储类别
12 - Non Combustible Liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Recent advances in catalytic asymmetric intermolecular oxidation of alkynes
Shen W-B and Tang X-T
Organic & Biomolecular Chemistry, 17(30), 7106-7113 (2019)
Iodine/TBHP-Promoted One-Pot Deoxygenation and Direct 2-Sulfonylation of Quinoline N-Oxides with Sodium Sulfinates: Facile and Regioselective Synthesis of 2-Sulfonylquinolines
Sumunnee L, et al.
European Journal of Organic Chemistry, 2017(5), 1025-1032 (2017)
Pascal Nösel et al.
Journal of the American Chemical Society, 135(41), 15662-15666 (2013-09-21)
In the presence of a gold catalyst an unprecedented oxidative cyclization of diynes takes place. The reaction cascade is initiated by an oxygen transfer from a N-oxide onto a gold-activated alkyne. The formed α-oxo carbene is transferred across the second
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