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Merck
CN

757330

锡(IV) 2,3-二氯化萘酞菁

99%

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经验公式(希尔记法):
C48H24Cl2N8Sn
化学文摘社编号:
分子量:
902.37
UNSPSC Code:
12352103
NACRES:
NA.23
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SMILES string

Cl[Sn]1(Cl)n2c3nc4nc(nc5n1c(nc6nc(nc2c7cc8ccccc8cc37)c9cc%10ccccc%10cc69)c%11cc%12ccccc%12cc5%11)c%13cc%14ccccc%14cc4%13

assay

99%

form

solid

mp

>300 °C (lit.), >500 °C

λmax

~875 nm (film)(lit.)

General description

Tin(IV) 2,3-naphthalocyanine dichloride (SnNcCl2) belongs to the family of metal based phthalocyanines. They are widely used as an electron donor material in organic photovoltaic (OPV) cells. The use of SnNcCl2 in OPVs increases its power conversion efficiencies since it absorbs light in the near infrared and infra-red portions of the electromagnetic spectrum which accounts for 50% of the solar photon flux.

Application

Used as an electron donor material in Organic Photovoltaic (OPV) Cells.

Features and Benefits

Has a narrow energy gap which helps in optical absorption beyond a wavelength of 1100 nm in the infrared region.

pictograms

Skull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Tandem organic photodetectors with tunable, broadband response.
Menke, S. M., Pandey, R., & Holmes, R. J.
Applied Physics Letters, 101(22), 223-301 (2012)
Tin naphthalocyanine complexes for infrared absorption in organic photovoltaic cells
Pandey, R., Kerner, R. A., Menke, S. M., Holst, J., Josyula, K. V., & Holmes, R. J.
Organic Electronics, 14(3), 804-808 (2013)

商品

While dye sensitization as the basis for color photography has been accepted for a very long time,1 attempts to use this principle for the conversion of solar light to electricity generally had resulted only in very low photocurrents, below 100 nA/cm

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