75854
D-苯基高丙氨酸乙酯 盐酸盐
≥98.0% (HPLC)
别名:
(-)-(R)-2-氨基-4-苯基丁酸乙酯 盐酸盐
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选择尺寸
关于此项目
经验公式（希尔记法）:
C12H17NO2 · HCl
化学文摘社编号:
分子量:
243.73
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
32160406
UNSPSC Code:
12352200
MDL number:
Beilstein/REAXYS Number:
8937583
InChI key
PTFKZMFFSIYCOV-RFVHGSKJSA-N
SMILES string
Cl.CCOC(=O)[C@H](N)CCc1ccccc1
InChI
1S/C12H17NO2.ClH/c1-2-15-12(14)11(13)9-8-10-6-4-3-5-7-10;/h3-7,11H,2,8-9,13H2,1H3;1H/t11-;/m1./s1
assay
≥98.0% (HPLC)
form
powder
optical activity
[α]/D -38.0±2.0°, c = 1 in H2O
reaction suitability
reaction type: solution phase peptide synthesis
application(s)
peptide synthesis
Application
D-Homophenylalanine ethyl ester hydrochloride may be used to synthesize (R)-2-amino-4-phenylbutan-1-ol, an intermediate for 2,6-bis[(4R)-4,5-dihydro-4-(2-phenylethyl)-2-oxazolyl]pyridine ligand.
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Synthesis of Chiral Pyridine Bis (Oxazoline) Ligands for Nickel?Catalyzed Asymmetric Negishi Cross?Couplings of Secondary Allylic Chlorides with Alkylzincs: 2, 6?Bis [(4R)?4, 5?Dihydro?4?(2?Phenylethyl)?2?Oxazolyl]?Pyridine
Lou S and Fu GC
Organic Syntheses, 310-316 (2010)
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