763365
2-(Dicyclohexylphosphino)-N,N-diisopropyl-1H-indole-1-carboxamide
97%
方案
97%
表单
solid
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
mp
191-196 °C
官能团
phosphine
SMILES字符串
CC(C)N(C(C)C)C(=O)n1c(cc2ccccc12)P(C3CCCCC3)C4CCCCC4
InChI
1S/C27H41N2OP/c1-20(2)28(21(3)4)27(30)29-25-18-12-11-13-22(25)19-26(29)31(23-14-7-5-8-15-23)24-16-9-6-10-17-24/h11-13,18-21,23-24H,5-10,14-17H2,1-4H3
InChI key
FDXSDIWDTPDIQJ-UHFFFAOYSA-N
应用
Effective ligand for cross-coupling of aryl chlorides
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Chau Ming So et al.
The Journal of organic chemistry, 73(19), 7803-7806 (2008-09-10)
This study describes a new class of indolylphosphine ligands, which can be easily accessed by a simple one-pot assembly from commercially available indoles, acid chlorides, and chlorophosphines. A combination of these three starting materials provides a high diversification of the
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