768561
Di-μ-chlorotetrakis[2-(1-isoquinolinyl-N)phenyl-C]diiridium(III)
95% (HPLC)
别名:
Iridium phenylquinoline dichloro-bridged dimer, [(pq)2IrCl]2
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关于此项目
经验公式（希尔记法）:
C60H40Cl2Ir2N4
化学文摘社编号:
分子量:
1272.33
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23
SMILES string
Cl[Ir].Cl[Ir].c1ccc(cc1)-c2nccc3ccccc23.c4ccc(cc4)-c5nccc6ccccc56.c7ccc(cc7)-c8nccc9ccccc89.c%10ccc(cc%10)-c%11nccc%12ccccc%11%12
InChI
1S/4C15H11N.2ClH.2Ir/c4*1-2-7-13(8-3-1)15-14-9-5-4-6-12(14)10-11-16-15;;;;/h4*1-11H;2*1H;;/q;;;;;;2*+1/p-2
InChI key
ZUKCRERFHSESIM-UHFFFAOYSA-L
assay
95% (HPLC)
form
solid
mp
440-455 °C
General description
Cyclometalated Ir complexes are good phosphorescent emitters. The strong spin-orbit coupling in the ir complex leads to phosphorescent lifetimes in the 1-10 μs range,high phosphorescent efficiencies at room temperature, and good color tunability of the emission energy.
The applications of such Ir complexes are based on the fact that neutral Ir based complexes consist of distinct carrier transporting/blocking and emitting layers. Single active layer in cationic Ir complexes is responsible for both carrier transport and light emission. Studies on anionic Ir are mainly focused on their photophysics.
The applications of such Ir complexes are based on the fact that neutral Ir based complexes consist of distinct carrier transporting/blocking and emitting layers. Single active layer in cationic Ir complexes is responsible for both carrier transport and light emission. Studies on anionic Ir are mainly focused on their photophysics.
Application
Some applications include the use of neutral Ir-based complexes in OLED structures and cationic Ir complexes in light-emitting electrochemical cells (LEC).
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Study of ion paired Iridium complexes (soft salts) and their application in organic Light emitting diodes
Journal of the American Ceramic Society. American Ceramic Society, 132(9), 3133-3139 (2010)
<SMALL>Tian, Nan; et al.</SMALL>
European Journal of Inorganic Chemistry, 30, 4875-4885 (2010)
Synthesis, Characterization, and Photophysical Properties of Iridium Complexes with an 8-Phenylquinoline Framework. The First Six-Membered Chelated Iridium Complexes for Electroluminance
Li HC, et al
Organometallics, 24, 1329-1335 (2005)
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