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769215

䓛

Name: 䓛
Brand: ALDRICH

别名:

1,2-Benzophenanthrene, Phenacene, Benzo[a]phenanthrene

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关于此项目

经验公式（希尔记法）:

C₁₈H₁₂

化学文摘社编号:

218-01-9

分子量:

228.29

UNSPSC Code:

12352200

NACRES:

NA.22

PubChem Substance ID:

329767436

EC Number:

205-923-4

Beilstein/REAXYS Number:

1909297

MDL number:

MFCD00003698

Form:

solid

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属性

form

solid

Quality Level

100

bp

448 °C (lit.)

mp

252-254 °C (lit.)

SMILES string

c1ccc2c(c1)ccc3c4ccccc4ccc23

InChI

1S/C18H12/c1-3-7-15-13(5-1)9-11-18-16-8-4-2-6-14(16)10-12-17(15)18/h1-12H

InChI key

WDECIBYCCFPHNR-UHFFFAOYSA-N

说明

Application

䓛可用作合成以下物质的结构单元：

基于䓛的四羧基取代的双[5]螺旋体通过双 Perkin 反应，之后进行 Pd 催化的环化。
基于䓛的 azahelicene 衍生物适用于钙钛矿太阳能电池。
3,6,9,12-四(4-叔-丁基苯基)䓛可作为OLED的蓝色发射器。

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pictograms

GHS08,GHS09

signalword

Danger

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

hcodes

H341,H350,H410,EUH441

pcodes

P201 - P202 - P273 - P308 + P313 - P391 - P501

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Muta. 2 - PBT - vPvB

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Chrysene-Based Azahelicene π-Linker of D-π-D-Type Hole-Transporting Materials for Perovskite Solar Cells.

Zefeng Tang et al.

ChemSusChem, 14(22), 4923-4928 (2021-10-13)

Chrysene is a readily available material for exploring new polycyclic aromatic hydrocarbons (PAHs). In this study, two chrysene based azahelicenes, nine-membered BA7 and ten-membered DA6, are constructed by intermolecular oxidative annulation of 6-aminochrysene and intramolecular annulation of N6 ,N12 -bis(1-chloronaphthalen-2-yl)chrysene-6,12-diamine

From chrysene to double [5] Helicenes

Bock H, et al.

European Journal of Organic Chemistry, 2015(5), 1033-1039 (2015)

A tetra-substituted chrysene: orientation of multiple electrophilic substitution and use of a tetra-substituted chrysene as a blue emitter for OLEDs.

Alex S Ionkin et al.

Chemical communications (Cambridge, England), (20), 2319-2321 (2008-05-14)

The first tetra-substituted non-fused chrysene, 3,6,9,12-tetrakis(4-tert-butylphenyl)chrysene with blue electroluminescence at 450 nm, and with a radiance of 500 cd m(-2), was synthesized by a two-step procedure: direct bromination of chrysene in trimethyl phosphate, followed by palladium-catalyzed cross-coupling of tetrabromochrysene and

全球贸易项目编号

货号	GTIN
769215-500MG	04061833552292
769215-1G	04061832924984