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Merck
CN

771244

Chloro{2,6-bis[(phenylseleno-Se)methyl]phenyl-C}palladium(II)

97%

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关于此项目

经验公式（希尔记法）:
C20H17ClPdSe2
化学文摘社编号:
761459-93-2
分子量:
557.14
NACRES:
NA.22
PubChem Substance ID:
329767481
UNSPSC Code:
12352300
MDL number:
MFCD22666457

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form

solid

InChI

1S/C20H17Se2.ClH.Pd/c1-3-10-19(11-4-1)21-15-17-8-7-9-18(14-17)16-22-20-12-5-2-6-13-20;;/h1-13H,15-16H2;1H;/q;;+1/p-1

SMILES string

Cl[Pd]c1c(C[Se]c2ccccc2)cccc1C[Se]c3ccccc3

InChI key

UPTIBUSNQPQCIY-UHFFFAOYSA-M

assay

97%

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

impurities

≤1% Dichloromethane

mp

162-221 °C

storage temp.

2-8°C

Application

Application Statement: Complex promotes the formation of alpha-amino acids and allyl alcohols through a Petasis Borono-Mannich reaction.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - STOT RE 2

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBC6866

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Nicklas Selander et al.
Journal of the American Chemical Society, 129(44), 13723-13731 (2007-10-13)
An efficient one-pot procedure was designed by integration of the pincer-complex-catalyzed borylation of allyl alcohols in the Petasis borono-Mannich reaction and in allylation of aldehydes and ketones. These procedures are suitable for one-pot synthesis of alpha-amino acids and homoallyl alcohols

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