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775444

三吡咯烷膦

Name: 三吡咯烷膦
Brand: ALDRICH

97%, liquid

别名:

Phosphorous acid tripyrrolidide, 三(N,N-四亚甲基)磷酰胺

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关于此项目

经验公式（希尔记法）:

C₁₂H₂₄N₃P

化学文摘社编号:

5666-12-6

分子量:

241.31

NACRES:

NA.22

PubChem Substance ID:

329767760

UNSPSC Code:

12352005

MDL number:

MFCD01863555

Beilstein/REAXYS Number:

1343311

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属性

产品名称

三吡咯烷膦, 97%

Quality Segment

100

assay

97%

form

liquid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

refractive index

n20/D 1.528, n20/D 1.53 (lit.)

bp

104 °C/0.1 mmHg (lit.)

density

1.041 at 25 °C, 1.049 g/mL at 25 °C (lit.)

functional group

phosphine

SMILES string

C1CCN(C1)P(N2CCCC2)N3CCCC3

InChI

1S/C12H24N3P/c1-2-8-13(7-1)16(14-9-3-4-10-14)15-11-5-6-12-15/h1-12H2

InChI key

PXFLCAQHOZXYED-UHFFFAOYSA-N

说明

Application

Monodentate P-donor ligand.

Used as a phosphitylation reagent for oligonucleotide synthesis.

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

209.8 °F

flash_point_c

98.8 °C

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Tris(N-pyrrolidinyl)phosphine substituted diiron dithiolate related to iron-only hydrogenase active site: Synthesis, characterization and electrochemical properties

Hou, J., et al.

Journal of Organometallic Chemistry, 691, 4633-4640 (2006)

Gene silencing activity of siRNA molecules containing phosphorodithioate substitutions.

Xianbin Yang et al.

ACS chemical biology, 7(7), 1214-1220 (2012-04-20)

Chemically synthesized small interfering RNAs (siRNAs) have been widely used to identify gene function and hold great potential in providing a new class of therapeutics. Chemical modifications are desired for therapeutic applications to improve siRNA efficacy. Appropriately protected ribonucleoside-3'-yl S-[β-(benzoylmercapto)ethyl]pyrrolidino-thiophosphoramidite

全球贸易项目编号

货号	GTIN
775444-2.5G	04061833340820
775444-500MG	04061833231678