775444
三吡咯烷膦
97%, liquid
别名:
Phosphorous acid tripyrrolidide, 三(N,N-四亚甲基)磷酰胺
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关于此项目
经验公式（希尔记法）:
C12H24N3P
化学文摘社编号:
分子量:
241.31
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Beilstein/REAXYS Number:
1343311
产品名称
三吡咯烷膦, 97%
InChI
1S/C12H24N3P/c1-2-8-13(7-1)16(14-9-3-4-10-14)15-11-5-6-12-15/h1-12H2
SMILES string
C1CCN(C1)P(N2CCCC2)N3CCCC3
InChI key
PXFLCAQHOZXYED-UHFFFAOYSA-N
assay
97%
form
liquid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
refractive index
n20/D 1.528
n20/D 1.53 (lit.)
bp
104 °C/0.1 mmHg (lit.)
density
1.041 at 25 °C
1.049 g/mL at 25 °C (lit.)
functional group
phosphine
Quality Level
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Application
Monodentate P-donor ligand.
Used as a phosphitylation reagent for oligonucleotide synthesis.
Used as a phosphitylation reagent for oligonucleotide synthesis.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
209.8 °F
flash_point_c
98.8 °C
Tris(N-pyrrolidinyl)phosphine substituted diiron dithiolate related to iron-only hydrogenase active site: Synthesis, characterization and electrochemical properties
Hou, J., et al.
Journal of Organometallic Chemistry, 691, 4633-4640 (2006)
Xianbin Yang et al.
ACS chemical biology, 7(7), 1214-1220 (2012-04-20)
Chemically synthesized small interfering RNAs (siRNAs) have been widely used to identify gene function and hold great potential in providing a new class of therapeutics. Chemical modifications are desired for therapeutic applications to improve siRNA efficacy. Appropriately protected ribonucleoside-3'-yl S-[β-(benzoylmercapto)ethyl]pyrrolidino-thiophosphoramidite
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