778583
叠氮苯 溶液
~0.5 M in 2-methyltetrahydrofuran, ≥95.0% (HPLC)
别名:
苯基叠氮化物 溶液
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关于此项目
经验公式（希尔记法）:
C6H5N3
化学文摘社编号:
分子量:
119.12
UNSPSC Code:
12352200
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
742248
Assay:
≥95.0% (HPLC)
Form:
liquid
InChI
1S/C6H5N3/c7-9-8-6-4-2-1-3-5-6/h1-5H
SMILES string
[N-]=[N+]=Nc1ccccc1
InChI key
CTRLRINCMYICJO-UHFFFAOYSA-N
assay
≥95.0% (HPLC)
form
liquid
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
concentration
~0.5 M in 2-methyltetrahydrofuran
impurities
≤2.0% water
greener alternative category
storage temp.
−20°C
Quality Level
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General description
Azidobenzene is an aromatic azide generally used in copper(I)-catalyzed azide-alkyne cycloaddition reactions.
Azidobenzene solution can undergo click reaction with alkyne-functionalized oligomers to form O-ester-functionalized o-phenylenes, a group of aromatic foldamers with a good folding tendency in most solvents.
Application
Phenylazide in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT RE 2
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
10.4 °F
flash_point_c
-12 °C
法规信息
危险化学品
此项目有
Solvent effects on the folding of o-phenylene oligomers
Vemuri GN, et al.
Organic & Biomolecular Chemistry, 15(4), 845-851 (2017)
Manabu Mizutani et al.
Biomacromolecules, 3(4), 668-675 (2002-07-09)
Photoreactive phenylazide-end-capped liquid copolymers were prepared by ring-opening copolymerization of epsilon-caprolactone (CL) and trimethylene carbonate (TMC) at an equimolar monomer feed ratio in the presence of a polyol, namely, a low-molecular-weight alcohol (di-, tri-, and tetraol) or poly(ethylene glycol) (PEG)
Jin Wang et al.
Organic letters, 9(20), 3973-3976 (2007-08-28)
Ultrafast photolysis (lambda(ex) = 308 nm) of phenyl azide in 100% formic acid produces a broadly absorbing transient within the instrument time resolution (300 fs), which is assigned to an excited state of the azide. The azide excited state fragments
David Evrard et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(30), 9286-9291 (2008-09-10)
The electrochemical reduction of phenylazide or phenylacetylene diazonium salts leads to the grafting of azido or ethynyl groups onto the surface of carbon electrodes. In the presence of copper(I) catalyst, these azide- or alkyne-modified surfaces react efficiently and rapidly with
Andrew L Hook et al.
Biomacromolecules, 10(3), 573-579 (2009-01-23)
The fabrication and characterization of chemical patterns using a technique that can be readily integrated with methods currently used for the formation of microarrays is presented. A high density poly(ethylene glycol) coating was deposited on glass slides as a background
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