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Merck
CN

778583

叠氮苯 溶液

greener alternative

~0.5 M in 2-methyltetrahydrofuran, ≥95.0% (HPLC)

别名:

苯基叠氮化物 溶液

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关于此项目

经验公式(希尔记法):
C6H5N3
化学文摘社编号:
分子量:
119.12
UNSPSC Code:
12352200
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
742248
Assay:
≥95.0% (HPLC)
Form:
liquid
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Quality Level

assay

≥95.0% (HPLC)

form

liquid

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

concentration

~0.5 M in 2-methyltetrahydrofuran

impurities

≤2.0% water

greener alternative category

storage temp.

−20°C

SMILES string

[N-]=[N+]=Nc1ccccc1

InChI

1S/C6H5N3/c7-9-8-6-4-2-1-3-5-6/h1-5H

InChI key

CTRLRINCMYICJO-UHFFFAOYSA-N

General description

Azidobenzene is an aromatic azide generally used in copper(I)-catalyzed azide-alkyne cycloaddition reactions.
Azidobenzene solution can undergo click reaction with alkyne-functionalized oligomers to form O-ester-functionalized o-phenylenes, a group of aromatic foldamers with a good folding tendency in most solvents.

Application

Disclaimer

Supply conditions do not apply to the regions and states of Brazil: North, Northeast, Mato Grosso do Sul, Mato Grosso, and Rio Grande do Sul.


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Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT RE 2

supp_hazards

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

10.4 °F

flash_point_c

-12 °C

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Solvent effects on the folding of o-phenylene oligomers
Vemuri GN, et al.
Organic & Biomolecular Chemistry, 15(4), 845-851 (2017)
Manabu Mizutani et al.
Biomacromolecules, 3(4), 668-675 (2002-07-09)
Photoreactive phenylazide-end-capped liquid copolymers were prepared by ring-opening copolymerization of epsilon-caprolactone (CL) and trimethylene carbonate (TMC) at an equimolar monomer feed ratio in the presence of a polyol, namely, a low-molecular-weight alcohol (di-, tri-, and tetraol) or poly(ethylene glycol) (PEG)
Andrew L Hook et al.
Biomacromolecules, 10(3), 573-579 (2009-01-23)
The fabrication and characterization of chemical patterns using a technique that can be readily integrated with methods currently used for the formation of microarrays is presented. A high density poly(ethylene glycol) coating was deposited on glass slides as a background



全球贸易项目编号

货号GTIN
778583-10ML04061838076311
778583-50ML04061838111692