Merck
CN
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文件

安全信息

778583

Sigma-Aldrich

叠氮苯 溶液

greener alternative

~0.5 M in 2-methyltetrahydrofuran, ≥95.0% (HPLC)

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别名:
苯基叠氮化物 溶液
经验公式（希尔记法）:
C6H5N3
CAS号:
622-37-7
分子量:
119.12
Beilstein:
742248
MDL编号:
MFCD00040895
PubChem化学物质编号:
329767981
NACRES:
NA.22

质量水平

100

检测方案

≥95.0% (HPLC)

形式

liquid

环保替代产品特性

Catalysis
Learn more about the Principles of Green Chemistry.

浓度

~0.5 M in 2-methyltetrahydrofuran

杂质

≤2.0% water

环保替代产品分类

Aligned,

储存温度

−20°C

SMILES string

[N-]=[N+]=Nc1ccccc1

InChI

1S/C6H5N3/c7-9-8-6-4-2-1-3-5-6/h1-5H

InChI key

CTRLRINCMYICJO-UHFFFAOYSA-N

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相关类别

一般描述

Azidobenzene is an aromatic azide generally used in copper(I)-catalyzed azide-alkyne cycloaddition reactions.
Azidobenzene solution can undergo click reaction with alkyne-functionalized oligomers to form O-ester-functionalized o-phenylenes, a group of aromatic foldamers with a good folding tendency in most solvents.

应用

Phenylazide in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

警示用语：

Danger

危险分类

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT RE 2

补充剂危害

EUH019

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

10.4 °F

闪点(°C)

-12 °C

法规信息

危险化学品

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Solvent effects on the folding of o-phenylene oligomers
Vemuri GN, et al.
Organic & Biomolecular Chemistry, 15(4), 845-851 (2017)
P Nahar et al.
Analytical biochemistry, 294(2), 148-153 (2001-07-11)
A simple and mild procedure is developed for the preparation of an activated polymer surface, used for immobilization of a protein ligand through a covalent linkage. Activation of the polymer surface is carried out by attaching an active functional group
Azmi Naqvi et al.
Analytical biochemistry, 327(1), 68-73 (2004-03-23)
We report a rapid and versatile procedure for the preparation of photoreactive polymers and light-induced immobilization of proteins onto such polymers. Photoreactive controlled-pore glass, silica gel, glass slide, and polystyrene microtiter plate are prepared in 40-60s by microwave irradiation of
Richard Wombacher et al.
Journal of the American Chemical Society, 130(27), 8594-8595 (2008-06-12)
The active site of a Diels-Alderase ribozyme is located in solution by photoaffinity cross-linking using a productlike azidobenzyl probe. Two key nucleotides are identified that contact the Diels-Alder product in a conformation-dependent fashion. The design of such probes does not
Manabu Mizutani et al.
Biomacromolecules, 3(4), 668-675 (2002-07-09)
Photoreactive phenylazide-end-capped liquid copolymers were prepared by ring-opening copolymerization of epsilon-caprolactone (CL) and trimethylene carbonate (TMC) at an equimolar monomer feed ratio in the presence of a polyol, namely, a low-molecular-weight alcohol (di-, tri-, and tetraol) or poly(ethylene glycol) (PEG)
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