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77913

(R)-(-)-1-甲氧基-2-丙醇

Name: (<I>R</I>)-(-)-1-甲氧基-2-丙醇
Brand: ALDRICH

≥98.5% (sum of enantiomers, GC)

别名:

(R)-(-)-丙二醇 1-甲醚

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关于此项目

经验公式（希尔记法）:

C₄H₁₀O₂

化学文摘社编号:

4984-22-9

分子量:

90.12

Beilstein/REAXYS Number:

1718941

UNSPSC Code:

12352112

NACRES:

NA.22

PubChem Substance ID:

57652688

MDL number:

MFCD01632587

Assay:

≥98.5% (sum of enantiomers, GC)

Form:

liquid

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属性

assay

≥98.5% (sum of enantiomers, GC)

form

liquid

optical activity

[α]20/D −22±2°, c = 10% in chloroform

refractive index

n20/D 1.403

bp

119-121 °C (lit.)

density

0.921 g/mL at 20 °C (lit.)

SMILES string

COC[C@@H](C)O

InChI

1S/C4H10O2/c1-4(5)3-6-2/h4-5H,3H2,1-2H3/t4-/m1/s1

InChI key

ARXJGSRGQADJSQ-SCSAIBSYSA-N

说明

General description

(R)-(-)-1-Methoxy-2-propanol is a chiral secondary alcohol. It is formed during the hydrolysis of (R)-1-methoxy-2-propyl-acetate in the presence of Candida antarctica lipase B.

Application

(R)-(-)-1-Methoxy-2-propanol can be used as a reactant to prepare:

(S)-3-(ethoxycarbonyl)-5-((1-methoxypropan-2-yl)oxy)benzoic acid, a key intermediate to synthesize phenylethyl benzamide derivatives, which can be used as glucokinase activators.
Chiral pyrazolopyrimidinone derivatives as potential phosphodiesterase enzyme (PDE5) inhibitors.
Aryl or alkyl ethers via etherification reaction.

pictograms

GHS02

signalword

Warning

hcodes

H226

pcodes

P210 - P233 - P240 - P241 - P242 - P243

Hazard Classifications

Flam. Liq. 3

存储类别

3 - Flammable liquids

wgk

WGK 1

flash_point_f

91.4 °F - closed cup

flash_point_c

33 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Nucleophilic Amination and Etherification of Aryl Alkyl Thioethers

Wang X, et al.

Organic Letters, 20(16), 4749-4753 (2018)

Highly potent and selective chiral inhibitors of PDE5: an illustration of Pfeiffer?s rule

Bunnage ME, et al.

Bioorganic & medicinal chemistry letters, 18(23), 6033-6036 (2008)

Kinetic modeling of lipase catalyzed hydrolysis of (R/S)-1-methoxy-2-propyl-acetate as a model reaction for production of chiral secondary alcohols.

Berendsen WR, et al.

Journal of Biotechnology, 121(2), 213-226 (2006)

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全球贸易项目编号

货号	GTIN
77913-5ML-F	04061837642272

主要文件

(R)-(-)-1-甲氧基-2-丙醇

≥98.5% (sum of enantiomers, GC)

选择尺寸

关于此项目

assay

form

optical activity

refractive index

bp

density

SMILES string

InChI

InChI key

General description

Application

安全信息

pictograms

signalword

hcodes

pcodes

Hazard Classifications

存储类别

wgk

flash_point_f

flash_point_c

ppe

法规信息

文件

分析证书(COA)

已有该产品？

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