77939
(R)-3,3′-Di-tert-butyl-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-(bi-2-naphthol) dipotassium salt
purum, ≥95.0% (dry substance, CHN)
等级
purum
方案
≥95.0% (dry substance, CHN)
表单
powder
杂质
<10% water
SMILES字符串
[K+].[K+].CC(C)(C)c1cc2CCCCc2c(c1[O-])-c3c([O-])c(cc4CCCCc34)C(C)(C)C
InChI
1S/C28H38O2.2K/c1-27(2,3)21-15-17-11-7-9-13-19(17)23(25(21)29)24-20-14-10-8-12-18(20)16-22(26(24)30)28(4,5)6;;/h15-16,29-30H,7-14H2,1-6H3;;/q;2*+1/p-2
InChI key
KUFMCCDFHGQYSN-UHFFFAOYSA-L
应用
Octahydro-BINOL was demonstrated to be an effective ligand in Mo-catalyzed desymmetrization of a triene by asymmetric ring closing metathesis.
包装
Bottomless glass bottle. Contents are inside inserted fused cone.
其他说明
A readily available user-friendly chiral catalyst for efficient enantioselective olefin metathesis, used in conjunction with Cat. No. 75287, a molybdenum complex
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Sarah J Dolman et al.
Journal of the American Chemical Society, 124(24), 6991-6997 (2002-06-13)
The first catalytic asymmetric ring-closing metathesis method for the synthesis of N-containing heterocycles is reported; this is accomplished through Mo-catalyzed kinetic resolution or desymmetrization of unsaturated amines. Importantly, this catalytic asymmetric method delivers medium-ring unsaturated amines (including eight-membered rings) in
S.L. Aeilts et al.
Angewandte Chemie (International Edition in English), 113, 1500-1500 (2001)
A Readily Available and User-Friendly Chiral Catalyst for Efficient Enantioselective Olefin Metathesis This research was supported by the National Institutes of Health (GM-59426) and the National Science Foundation (CHE-9905806 to A. H. H. and CHE-9988766 to R. R. S.).
Sarah L. Aeilts et al.
Angewandte Chemie (International ed. in English), 40(8), 1452-1456 (2001-04-24)
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