跳转至内容
Merck
CN

77939

(R)-3,3′-Di-tert-butyl-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-(bi-2-naphthol) dipotassium salt

purum, ≥95.0% (dry substance, CHN)

登录 查看组织和合同定价。

选择尺寸

关于此项目

经验公式（希尔记法）:
C28H36K2O2
化学文摘社编号:
350683-75-9
分子量:
482.78
UNSPSC Code:
12352002
PubChem Substance ID:
329768034
MDL number:
MFCD03788939

主要文件

查看所有文档
技术服务
需要帮助？我们经验丰富的科学家团队随时乐意为您服务。
让我们为您提供帮助
技术服务
需要帮助？我们经验丰富的科学家团队随时乐意为您服务。
让我们为您提供帮助

InChI

1S/C28H38O2.2K/c1-27(2,3)21-15-17-11-7-9-13-19(17)23(25(21)29)24-20-14-10-8-12-18(20)16-22(26(24)30)28(4,5)6;;/h15-16,29-30H,7-14H2,1-6H3;;/q;2*+1/p-2

SMILES string

[K+].[K+].CC(C)(C)c1cc2CCCCc2c(c1[O-])-c3c([O-])c(cc4CCCCc34)C(C)(C)C

InChI key

KUFMCCDFHGQYSN-UHFFFAOYSA-L

grade

purum

assay

≥95.0% (dry substance, CHN)

form

powder

impurities

<10% water

Application

Octahydro-BINOL was demonstrated to be an effective ligand in Mo-catalyzed desymmetrization of a triene by asymmetric ring closing metathesis.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

A readily available user-friendly chiral catalyst for efficient enantioselective olefin metathesis, used in conjunction with Cat. No. 75287, a molybdenum complex

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

法规信息

新产品
此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
439388/1

没有发现合适的版本？

如果您需要特殊版本，可通过批号或批次号查找具体证书。

搜索COA

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

Sarah J Dolman et al.
Journal of the American Chemical Society, 124(24), 6991-6997 (2002-06-13)
The first catalytic asymmetric ring-closing metathesis method for the synthesis of N-containing heterocycles is reported; this is accomplished through Mo-catalyzed kinetic resolution or desymmetrization of unsaturated amines. Importantly, this catalytic asymmetric method delivers medium-ring unsaturated amines (including eight-membered rings) in
A Readily Available and User-Friendly Chiral Catalyst for Efficient Enantioselective Olefin Metathesis This research was supported by the National Institutes of Health (GM-59426) and the National Science Foundation (CHE-9905806 to A. H. H. and CHE-9988766 to R. R. S.).
Sarah L. Aeilts et al.
Angewandte Chemie (International ed. in English), 40(8), 1452-1456 (2001-04-24)
S.L. Aeilts et al.
Angewandte Chemie (International Edition in English), 113, 1500-1500 (2001)

我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系客户支持