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Merck
CN

790524

2-[7-（4-二苯基氨基苯基）-2,1,3-苯并噻二唑-4-基]亚甲基丙二腈

96%

别名:

2-((7-(4-(二苯基氨基）苯基）苯并[c][1,2,5]噻二唑-4-基）亚甲基）丙二腈, DPDCPB

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关于此项目

经验公式（希尔记法）:
C28H17N5S
化学文摘社编号:
1393343-60-6
分子量:
455.53
MDL编号:
MFCD27978257
UNSPSC代码:
12352103
PubChem化学物质编号:
329768220
NACRES:
NA.23

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方案

96%

表单

solid

mp

203-207 °C

λmax

549 nm in dichloromethane

半导体性质

P-type

SMILES字符串

N#CC(C#N)=CC1=CC=C(C2=CC=C(N(C3=CC=CC=C3)C4=CC=CC=C4)C=C2)C5=NSN=C15

InChI

1S/C28H17N5S/c29-18-20(19-30)17-22-13-16-26(28-27(22)31-34-32-28)21-11-14-25(15-12-21)33(23-7-3-1-4-8-23)24-9-5-2-6-10-24/h1-17H

InChI key

FWTUEQONZCDFRW-UHFFFAOYSA-N

应用

使用这种新型供体-受体-受体（D-A-A）供体分子的真空沉积有机太阳能电池；DPDCPB；与电子受体C60/C70结合使用，实现了5.6%的创纪录的高功率转换效率(PCE)。

设备结构：
MoO3（30nm) / DPDCPB（7nm) / DPDCPB:C70（40nm) / C70（7nm) / BCP（10nm) / Ag（150nm)

设备性能：
  • JSC = 11.45 mA/cm2
  • VOC = 1.0 V
  • FF = 0.5
  • PCE = 5.6%

象形图

Exclamation mark
GHS07

警示用语：

Warning

预防措施声明

P261 - P305 + P351 + P338

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKBQ5847V

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Yi-Hong Chen et al.
Journal of the American Chemical Society, 134(33), 13616-13623 (2012-07-27)
Three new tailor-made molecules (DPDCTB, DPDCPB, and DTDCPB) were strategically designed and convergently synthesized as donor materials for small-molecule organic solar cells. These compounds possess a donor-acceptor-acceptor molecular architecture, in which various electron-donating moieties are connected to an electron-withdrawing dicyanovinylene
Li-Yen Lin et al.
Journal of the American Chemical Society, 133(40), 15822-15825 (2011-09-13)
A novel donor-acceptor-acceptor (D-A-A) donor molecule, DTDCTB, in which an electron-donating ditolylaminothienyl moiety and an electron-withdrawing dicyanovinylene moiety are bridged by another electron-accepting 2,1,3-benzothiadiazole block, has been synthesized and characterized. A vacuum-deposited organic solar cell employing DTDCTB combined with the

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Development of Small Molecule Donors for Solution-Processed Organic Solar Cells

Solution-processed organic photovoltaic devices (OPVs) have emerged as a promising clean energy generating technology due to their ease of fabrication, potential to enable low-cost manufacturing via printing or coating techniques, and ability to be incorporated onto light weight, flexible substrates.

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