790796
Zinc benzylsulfinate
别名:
Zinc benzylsulfinate, Baran BNS Reagent
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关于此项目
经验公式（希尔记法）:
C14H14O4S2Zn
化学文摘社编号:
分子量:
375.78
UNSPSC Code:
12352002
PubChem Substance ID:
NACRES:
NA.22
Form:
solid
SMILES string
O=S(O[Zn]OS(CC1=CC=CC=C1)=O)CC2=CC=CC=C2
InChI
1S/2C7H8O2S.Zn/c2*8-10(9)6-7-4-2-1-3-5-7;/h2*1-5H,6H2,(H,8,9);/q;;+2/p-2
InChI key
AHSIXHPQMGLVIG-UHFFFAOYSA-L
form
solid
reaction suitability
reaction type: Alkylations, reaction type: C-C Bond Formation, reagent type: catalyst
reaction type: C-H Activation, reagent type: diversification reagent
mp
56 °C (Decomposition)
storage temp.
2-8°C
Application
Zinc benzylsulfinate (BNS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.
Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles
Learn More at the Professor and Product Portal of Professor Phil S. Baran.
Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles
Learn More at the Professor and Product Portal of Professor Phil S. Baran.
Other Notes
may contain up to 1 mole eq ZnCl2
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Fionn O'Hara et al.
Journal of the American Chemical Society, 135(32), 12122-12134 (2013-07-19)
Radical addition processes can be ideally suited for the direct functionalization of heteroaromatic bases, yet these processes are only sparsely used due to the perception of poor or unreliable control of regiochemistry. A systematic investigation of factors affecting the regiochemistry
Yuta Fujiwara et al.
Nature, 492(7427), 95-99 (2012-12-04)
Nitrogen-rich heterocyclic compounds have had a profound effect on human health because these chemical motifs are found in a large number of drugs used to combat a broad range of diseases and pathophysiological conditions. Advances in transition-metal-mediated cross-coupling have simplified
商品
Rapidly diversify (hetero)aromatic scaffolds for chemical industry needs amid resource and time constraints, ensuring efficiency.
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