Phenofluor ^™溶液

Name: Phenofluor <SUP>™</SUP>溶液
Brand: ALDRICH

0.1 M in toluene

别名:

1,3-Bis(2,6-diisopropylphenyl)-2,2-difluoro-4-imidazoline

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关于此项目

经验公式（希尔记法）:

C₂₇H₃₆F₂N₂

分子量:

426.58

UNSPSC Code:

12352101

PubChem Substance ID:

329768478

NACRES:

NA.22

MDL number:

MFCD22377831

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产品名称

Phenofluor ^™溶液, 0.1 M in toluene

SMILES string

FC1(N(C=CN1c3c(cccc3C(C)C)C(C)C)c2c(cccc2C(C)C)C(C)C)F

InChI

1S/C27H36F2N2/c1-17(2)21-11-9-12-22(18(3)4)25(21)30-15-16-31(27(30,28)29)26-23(19(5)6)13-10-14-24(26)20(7)8/h9-20H,1-8H3

InChI key

FQXXWTOSPDVNSG-UHFFFAOYSA-N

form

liquid

concentration

0.1 M in toluene

density

0.865 g/mL at 25 °C

functional group

fluoro

storage temp.

2-8°C

Quality Level

100

Application

Facile deoxyfluorination of phenols without preactivation (), along with highly chemoselective deoxyfluorination of highly functionalized late-stage intermediates ().

Legal Information

PhenoFluor is a trademark of SciFluor Life Sciences, LLC

pictograms

GHS02,GHS08,GHS07

signalword

Danger

hcodes

H225,H304,H315,H336,H361d,H373,H412

pcodes

P201 - P210 - P273 - P301 + P310 + P331 - P302 + P352 - P308 + P313

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

target_organs

Central nervous system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

39.2 °F

flash_point_c

4 °C

法规信息

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Late-stage deoxyfluorination of alcohols with PhenoFluor.

Filippo Sladojevich et al.

Journal of the American Chemical Society, 135(7), 2470-2473 (2013-02-13)

An operationally simple protocol for the selective deoxyfluorination of structurally complex alcohols is presented. Several fluorinated derivatives of natural products and pharmaceuticals have been prepared to showcase the potential of the method for late-stage diversification and its functional group compatibility.

Deoxyfluorination of phenols.

Pingping Tang et al.

Journal of the American Chemical Society, 133(30), 11482-11484 (2011-07-09)

An operationally simple ipso fluorination of phenols with a new deoxyfluorination reagent is presented.

商品

PhenoFluor™ Deoxyfluorination Solution

PhenoFluor^™ enables one-step conversion of phenols to aryl fluorides, facilitating fluorination without pre-activation.

Phenofluor ^™溶液

0.1 M in toluene