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795291

Phenofluor ™溶液

0.1 M in toluene

别名:

1,3-Bis(2,6-diisopropylphenyl)-2,2-difluoro-4-imidazoline

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关于此项目

经验公式（希尔记法）:
C27H36F2N2
分子量:
426.58
UNSPSC Code:
12352101
PubChem Substance ID:
329768478
NACRES:
NA.22
MDL number:
MFCD22377831
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form

liquid

Quality Level

100

concentration

0.1 M in toluene

density

0.865 g/mL at 25 °C

functional group

fluoro

storage temp.

2-8°C

SMILES string

FC1(N(C=CN1c3c(cccc3C(C)C)C(C)C)c2c(cccc2C(C)C)C(C)C)F

InChI

1S/C27H36F2N2/c1-17(2)21-11-9-12-22(18(3)4)25(21)30-15-16-31(27(30,28)29)26-23(19(5)6)13-10-14-24(26)20(7)8/h9-20H,1-8H3

InChI key

FQXXWTOSPDVNSG-UHFFFAOYSA-N

Application

Facile deoxyfluorination of phenols without preactivation (), along with highly chemoselective deoxyfluorination of highly functionalized late-stage intermediates ().

Legal Information

PhenoFluor is a trademark of SciFluor Life Sciences, LLC
PhenoFluor is a trademark of SciFluor Life Sciences, LLC

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

target_organs

Central nervous system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

39.2 °F

flash_point_c

4 °C

法规信息

新产品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBS1844
SHBR2031
SHBP3792
SHBP6176
SHBK7188

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商品

PhenoFluor™ Deoxyfluorination Solution

PhenoFluor™ enables one-step conversion of phenols to aryl fluorides, facilitating fluorination without pre-activation.

相关内容

Ritter Group – Professor Product Portal

The Ritter lab currently focuses on fluorination chemistry for late-stage functionalization of complex natural and unnatural products. PhenoFluor™ has been developed as a general reagent for the selective, predictable, direct deoxyfluorination of complex alcohols and phenols.

Filippo Sladojevich et al.
Journal of the American Chemical Society, 135(7), 2470-2473 (2013-02-13)
An operationally simple protocol for the selective deoxyfluorination of structurally complex alcohols is presented. Several fluorinated derivatives of natural products and pharmaceuticals have been prepared to showcase the potential of the method for late-stage diversification and its functional group compatibility.
Pingping Tang et al.
Journal of the American Chemical Society, 133(30), 11482-11484 (2011-07-09)
An operationally simple ipso fluorination of phenols with a new deoxyfluorination reagent is presented.

全球贸易项目编号

货号GTIN
795291-10ML04061832954202