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Merck
CN

795631

Sigma-Aldrich

Mesitylene pentamethylcyclopentadienyl ruthenium dimer

别名:

[RuCp*(mes)]2

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关于此项目

经验公式(希尔记法):
C38H54Ru2
分子量:
712.98
UNSPSC代码:
12352103
PubChem化学物质编号:
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表单

solid

储存温度

−20°C

SMILES字符串

C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C.C[C]3C(C4[C](C)[C][C](C)[C][C]4C)[C](C)[C][C](C)[C]3.[Ru].[Ru]

InChI

1S/C18H24.2C10H15.2Ru/c1-11-7-13(3)17(14(4)8-11)18-15(5)9-12(2)10-16(18)6;2*1-6-7(2)9(4)10(5)8(6)3;;/h7-10,17-18H,1-6H3;2*1-5H3;;

InChI key

MIUITKYUOGVLMU-UHFFFAOYSA-N

应用

Used as an air-stable n-dopant for organic electronic devices.

储存分类代码

13 - Non Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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分析证书(COA)

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Selina Olthof et al.
Physical review letters, 109(17), 176601-176601 (2012-12-12)
Tail states in organic semiconductors have a significant influence on device performances by acting as traps in charge transport. We present a study of the controlled passivation of acceptor tail states in fullerene C(60) by the addition of electrons introduced
Passivation of trap states in unpurified and purified C60 and the influence on organic field-effect transistor performance
Olthof, S.;
Applied Physics Letters, 101, 253303-253303 (2012)
n-Doping of Organic Electronic Materials Using Air-Stable Organometallics: A Mechanistic Study of Reduction by Dimeric Sandwich Compounds
Guo, S.;
Chemistry (Weinheim An Der Bergstrasse, Germany), 18, 14760-14760 (2012)
Song Guo et al.
Advanced materials (Deerfield Beach, Fla.), 24(5), 699-703 (2011-11-08)
Air-stable dimers of sandwich compounds including rhodocene and (pentamethylcyclopentadienyl)(arene)ruthenium and iron derivatives can be used for n-doping electron-transport materials with electron affinities as small as 2.8 eV. A p-i-n homojunction diode based on copper phthalocyanine and using rhodocene dimer as

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