798835
[Ru(phd)3](PF6)2
别名:
Tris(1,10-phenanthroline-5,6-dione)ruthenium(II) bis(hexafluorophosphate)
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关于此项目
经验公式（希尔记法）:
C36H18F12N6O6P2Ru
化学文摘社编号:
分子量:
1021.56
UNSPSC Code:
12352202
PubChem Substance ID:
NACRES:
NA.22
SMILES string
F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.O=C1C2=C(C3=NC=CC=C3C1=O)N=CC=C2.O=C4C(C=CC=N5)=C5C6=C(C4=O)C=CC=N6.O=C7C8=CC=CN=C8C9=C(C7=O)C=CC=N9.[Ru+2]
InChI
1S/3C12H6N2O2.2F6P.Ru/c3*15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10;2*1-7(2,3,4,5)6;/h3*1-6H;;;/q;;;2*-1;+2
InChI key
LGAOGZFZNIEFHF-UHFFFAOYSA-N
form
powder
reaction suitability
core: ruthenium, reagent type: catalyst
Application
In combination with Co(salophen), (Aldrich 345652), [Ru(phd)3](PF6)2 is utilized in the aerobic oxidation of tetrahydroquinolines at room temperature to form quinolines. Unlike previous catalyst systems, the reported application is highly efficient under the presence of atmospheric oxygen.
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
相关内容
he Stahl Lab focuses on the development of catalysts and catalytic reactions for selective oxidation of organic molecules, with particular emphasis on aerobic oxidation reactions.
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