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About This Item
经验公式（希尔记法）:
C39H41MnN3P2
CAS Number:
分子量:
668.65
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
表单
powder
反应适用性
core: manganese
reagent type: catalyst
mp
>200 °C
储存温度
2-8°C
SMILES字符串
C/C(C1=CC=CC(/C(C)=N/CCCP(C2=CC=CC=C2)C3=CC=CC=C3)=N1)=N\CCCP(C4=CC=CC=C4)C5=CC=CC=C5.[Mn]
InChI
1S/C39H41N3P2.Mn/c1-32(40-28-16-30-43(34-18-7-3-8-19-34)35-20-9-4-10-21-35)38-26-15-27-39(42-38)33(2)41-29-17-31-44(36-22-11-5-12-23-36)37-24-13-6-14-25-37;/h3-15,18-27H,16-17,28-31H2,1-2H3;/b40-32+,41-33+;
InChI key
HGQXTZFURCAPHA-PVFFQWOCSA-N
一般描述
Trovitch Mn-Precatalyst [((Ph2PPr)PDI)Mn] is a formally zerovalent manganese complex, containing phosphine-substituted PDI (pyridine diimine) ligand. This hydrosilylation reagent can be synthesized by the reduction of (Ph2PPrPDI)MnCl2. Its electronic structure has been studied. Trovitch Mn-Precatalyst is also reported to mediate the dihydrosilylation of esters.
应用
Mn-complex was commercialized in collaboration with Ryan Trovitch and coworkers. This complex has shown to be effective in the hydrosilylation of ketones and esters.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
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