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Merck
CN

798975

Trovitch Ni-Precatalyst

别名:

(Ph2PPrDI)Ni

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关于此项目

经验公式(希尔记法):
C34H38N2NiP2
化学文摘社编号:
分子量:
595.32
PubChem Substance ID:
UNSPSC Code:
12161600
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form

powder

reaction suitability

core: nickel, reagent type: catalyst

storage temp.

2-8°C

SMILES string

CC(/C(C)=N/CCCP(C1=CC=CC=C1)C2=CC=CC=C2)=N\CCCP(C3=CC=CC=C3)C4=CC=CC=C4.[Ni]

InChI

1S/C34H38N2P2.Ni/c1-29(35-25-15-27-37(31-17-7-3-8-18-31)32-19-9-4-10-20-32)30(2)36-26-16-28-38(33-21-11-5-12-22-33)34-23-13-6-14-24-34;/h3-14,17-24H,15-16,25-28H2,1-2H3;/b35-29+,36-30+;

InChI key

ILRLBVPENGSFTO-CAKVIZMISA-N



存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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商品

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

相关内容

The Trovitch laboratory is working to develop first-row transition metal catalysts that can be used to achieve a variety of organic transformations. The first complexes from this group made available through Sigma-Aldrich are the hydrosilylation catalysts, (Ph2PPrPDI)Mn and (Ph2PPrDI)Ni. Although these compounds are formally zerovalent, both feature a reduced chelate that coordinates to the metal center beyond its redox non-innocent core.





全球贸易项目编号

货号GTIN
798975-100MG04061833243404