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Merck
CN

799505

Sigma-Aldrich

Ethane diamine cycloimine organic cage

别名:

CC1, Cage 1

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关于此项目

经验公式(希尔记法):
C48H48N12
化学文摘社编号:
分子量:
792.98
UNSPSC代码:
26111700
PubChem化学物质编号:
NACRES:
NA.23
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方案

>98%

表单

powder

储存温度

2-8°C

SMILES字符串

C1(/C=N/CC/N=C/C2=CC(/C=N/CC/N=C/3)=CC(/C=N/CC/N=C/4)=C2)=CC(/C=N/CC/N=C/C5=CC4=CC6=C5)=CC(/C=N/CC/N=C/C7=CC3=CC(/C=N/CC/N=C/6)=C7)=C1

InChI

1S/C48H48N12/c1-2-50-26-38-15-41-18-42(16-38)30-54-8-10-58-34-46-20-44-22-48(24-46)36-60-12-11-59-35-47-21-43(19-45(23-47)33-57-9-7-53-29-41)31-55-5-3-51-27-39-13-37(25-49-1)14-40(17-39)28-52-4-6-56-32-44/h13-36H,1-12H2/b49-25+,50-26+,51-27+,52-28+,53-29+,54-30+,55-31+,56-32+,57-33+,58-34+,59-35+,60-36+

InChI key

GUTZSUDNSFKJNV-WMKISWKQSA-N

应用

Cage-MOFs are metal organic frameworks (MOFs) having porous organic ligands. The CC1 cage finds applications as organic linker for ‘Cage-MOFs′ synthesis.

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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分析证书(COA)

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Shashikala I Swamy et al.
Journal of the American Chemical Society, 132(37), 12773-12775 (2010-08-28)
We report here the synthesis of a metal-organic framework comprising an organic cage linker with covalently prefabricated, intrinsic porosity. The network can be compared to a porous rock salt structure where the pores are partially filled by charge-balancing cations.
Jamie L Culshaw et al.
Journal of the American Chemical Society, 135(27), 10007-10010 (2013-06-22)
A simple, one-step amidation reaction is used to produce a range of 12-arm organic building blocks for supramolecular chemistry via the derivatization of porous imine cages. As an example, microporous dendrimers are prepared.
Tomokazu Tozawa et al.
Nature materials, 8(12), 973-978 (2009-10-27)
Porous materials are important in a wide range of applications including molecular separations and catalysis. We demonstrate that covalently bonded organic cages can assemble into crystalline microporous materials. The porosity is prefabricated and intrinsic to the molecular cage structure, as

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