InChI
1S/C36H54N2O2.ClH.Co/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/q;;+3/p-3/b37-21+,38-22+;;/t29-,30-;;/m0../s1
InChI key
DIPYCKRNYQWVPM-RUIQGICGSA-K
SMILES string
Cl[Co]1OC(C(C(C)(C)C)=CC(C(C)(C)C)=C2)=C2/C=N/[C@](CCCC3)([H])[C@@]3([H])/N=C/C(C=C(C(C)(C)C)C=C4C(C)(C)C)=C4O1
form
powder
reaction suitability
reagent type: catalyst
core: cobalt
mp
250 °C
storage temp.
2-8°C
Application
When utilized with organosilanes, catalytic amounts of Co(salen,t-Bu, t-Bu)Cl effects the isomerization of terminal alkenes.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Steven W M Crossley et al.
Journal of the American Chemical Society, 136(48), 16788-16791 (2014-11-15)
Catalytic amounts of Co(Sal(tBu,tBu))Cl and organosilane irreversibly isomerize terminal alkenes by one position. The same catalysts effect cycloisomerization of dienes and retrocycloisomerization of strained rings. Strong Lewis bases like amines and imidazoles, and labile functionalities like epoxides, are tolerated.
相关内容
Shenvi lab repurposed Jacobsen’s cobalt chloride complex for positional isomerization of terminal alkenes via reversible hydrogen atom transfer.
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持