804576
(1E)-4-Hydroxy-1-mesityl-4-methylpent-1-en-3-one
别名:
Bode Hydroxamic Acid
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关于此项目
经验公式（希尔记法）:
C15H20O2
化学文摘社编号:
分子量:
232.32
UNSPSC Code:
12352000
PubChem Substance ID:
NACRES:
NA.22
SMILES string
O=C(C(C)(C)O)/C=C/C1=C(C)C=C(C)C=C1C
InChI
1S/C15H20O2/c1-10-8-11(2)13(12(3)9-10)6-7-14(16)15(4,5)17/h6-9,17H,1-5H3/b7-6+
InChI key
MZEPKOZFBZWACD-VOTSOKGWSA-N
form
crystals
mp
75-77 °C
functional group
hydroxyl
ketone
Application
The following hydroxamic acid was shown by Bode and coworkers to assist in the kinetic resolution of cyclic amines through acylation of one enantiomer, which can be controlled using either the (R,S)- or (S,R)-Bode Kinetic Resolution Catalyst, both of which are also available through Sigma-Aldrich.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
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相关内容
Bode Group creates N-mesityl-NHC catalysts for enantioselective annulations and SnAP reagents for one-pot aldehyde conversion into N-heterocycles.
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