表单
powder
mp
170-175 °C (d)
SMILES字符串
O=C(B(F)(F)F)C1=COC=C1.[K]
InChI
1S/C5H3BF3O2.K.H/c7-6(8,9)5(10)4-1-2-11-3-4;;/h1-3H;;
InChI key
HZMYTFNRKCJBQK-UHFFFAOYSA-N
一般描述
Potassium 3-furoyltrifluoroborate belongs to the class of compounds known as potassium acyltrifluroborates (KATs). This heteraroyl trifluoroborate salt is stable and does not readily undergo trimerization.
应用
Potassium acyltrifluroborates (KATs) are bench, air, and moisture stable reagents for rapid, chemoselective amide bond formations with hydroxylamines. These amide bond forming reactions proceed under aqueous conditions, without the need for coupling reagents or protecting groups. This product was introduced in collaboration with the Bode Research Group.
其他说明
Synthesis of Chemically and Configurationally Stable Monofluoro Acylboronates: Effect of Ligand Structure on their Formation, Properties, and Reactivities
Rapid Ligations with Equimolar Reactants in Water with the Potassium Acyltrifluoroborate (KAT) Amide Formation
Amide-Forming Ligation of Acyltrifluoroborates and Hydroxylamines in Water
Rapid Ligations with Equimolar Reactants in Water with the Potassium Acyltrifluoroborate (KAT) Amide Formation
Amide-Forming Ligation of Acyltrifluoroborates and Hydroxylamines in Water
警示用语：
Warning
危险声明
预防措施声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
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