SMILES string
O=C(B(F)(F)F)C1=COC=C1.[K]
InChI
1S/C5H3BF3O2.K.H/c7-6(8,9)5(10)4-1-2-11-3-4;;/h1-3H;;
InChI key
HZMYTFNRKCJBQK-UHFFFAOYSA-N
form
powder
mp
170-175 °C (d)
Application
Potassium acyltrifluroborates (KATs) are bench, air, and moisture stable reagents for rapid, chemoselective amide bond formations with hydroxylamines. These amide bond forming reactions proceed under aqueous conditions, without the need for coupling reagents or protecting groups. This product was introduced in collaboration with the Bode Research Group.
General description
Potassium 3-furoyltrifluoroborate belongs to the class of compounds known as potassium acyltrifluroborates (KATs). This heteraroyl trifluoroborate salt is stable and does not readily undergo trimerization.
Other Notes
Synthesis of Chemically and Configurationally Stable Monofluoro Acylboronates: Effect of Ligand Structure on their Formation, Properties, and Reactivities
Rapid Ligations with Equimolar Reactants in Water with the Potassium Acyltrifluoroborate (KAT) Amide Formation
Amide-Forming Ligation of Acyltrifluoroborates and Hydroxylamines in Water
Rapid Ligations with Equimolar Reactants in Water with the Potassium Acyltrifluoroborate (KAT) Amide Formation
Amide-Forming Ligation of Acyltrifluoroborates and Hydroxylamines in Water
signalword
Warning
hcodes
pcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
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