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Merck
CN

805394

FK 209 Co(III) TFSI salt

别名:

三(2-(1H-吡唑-1-基)-4-丁基吡啶)钴(III)三[双(三氟甲烷)磺酰亚胺]

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关于此项目

经验公式(希尔记法):
C42H45CoF18O12N12S6
分子量:
1503.17
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23
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方案

98%

质量水平

表单

powder

mp

281.5 °C (exp.)

SMILES字符串

O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.CC(C)(C)C1=CC(N2N=CC=C2)=NC=C1.CC(C)(C)C3=CC=NC(N4C=CC=N4)=C3.CC(C)(C)C5=CC=NC(N6C=CC=N6)=C5.C

InChI key

PZTBQPSYUSXHSB-UHFFFAOYSA-N

一般描述

FK 209 Co(III) TFSI盐(FK 209)是一种钴(III)配合物,可以用作空穴传输材料用p型掺杂剂,使功率转换效率达9-12%。

应用

FK 209可用于诱导PCDTBT和spiro-OMeTAD的p型掺杂,用于制造效率达15-16%的钙钛矿太阳能电池(PSC)的空穴传输材料。
用这种钴配合物大幅度提高液体电解质电池的光电压,或通过固态光伏器件实现超高性能。

象形图

Exclamation mark

警示用语:

Warning

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

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Efficient perovskite photovoltaic devices using chemically doped PCDTBT as a hole-transport material.
Wong-Stringer M, et al.
Journal of Material Chemistry A, 5(30), 15714-15723 (2017)
Acid additives enhancing the conductivity of spiro-OMeTAD toward high-efficiency and hysteresis-less planar perovskite solar cells.
Li Z, et al.
Advanced Energy Materials, 7, 15714-15723 (2016)
Co (III) complexes as p-dopants in solid-state dye-sensitized solar cells
Burschka J, et al.
Chemistry of Materials, 25(15), 2986-2990 (2013)
Teck Ming Koh et al.
ChemSusChem, 7(7), 1909-1914 (2014-05-23)
In this work, we report a new cobalt(III) complex, tris[2-(1H-pyrazol-1-yl)pyrimidine]cobalt(III) tris[bis(trifluoromethylsulfonyl)imide] (MY11), with deep redox potential (1.27 V vs NHE) as dopant for 2,2',7,7'-tetrakis-(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-OMeTAD). This dopant possesses, to the best of our knowledge, the deepest redox potential among all
Edoardo Mosconi et al.
Journal of the American Chemical Society, 134(47), 19438-19453 (2012-11-02)
We report a combined experimental and computational investigation to understand the nature of the interactions between cobalt redox mediators and TiO(2) surfaces sensitized by ruthenium and organic dyes, and their impact on the performance of the corresponding dye-sensitized solar cells

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