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Merck
CN

805521

FK 269 Co(III) PF6 salt

别名:

Greatcell Solar®

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关于此项目

经验公式（希尔记法）:
C22H18CoF18N10P3
分子量:
916.27
UNSPSC Code:
12352103
PubChem Substance ID:
329768944
NACRES:
NA.23

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SMILES string

F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.C1(N2N=CC=C2)=CC=CC(N3C=CC=N3)=N1.N4(C5=NC(N6N=CC=C6)=CC=C5)N=CC=C4.[Co+3]

InChI

1S/2C11H9N5.Co.3F6P/c2*1-4-10(15-8-2-6-12-15)14-11(5-1)16-9-3-7-13-16;;3*1-7(2,3,4,5)6/h2*1-9H;;;;/q;;+3;3*-1

InChI key

GCYMTAFZAULUPX-UHFFFAOYSA-N

assay

98%

form

powder

mp

355 °C

Application

Use this cobalt complexes to increase photovoltages of liquid electrolyte cells substantially or to achieve ultrahigh performance with solid state photovoltaic devices, such as perovskite and dye-sensitized solar cells.
FK 269 cobalt complexes offer guaranteed performance, high reproducibility, consistent results, and are of highest purity. In comparison to triiodide-based redox electrolytes, cobalt complexes in general increase photovoltages and, particularly at lower light levels (e.g. for indoor applications), significantly increase device power output.

Legal Information

Product of Greatcell Solar®
Greatcell Solar is a registered trademark of Greatcell Solar

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKBW6108V

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Sandra M Feldt et al.
Physical chemistry chemical physics : PCCP, 15(19), 7087-7097 (2013-04-05)
Regeneration and recombination kinetics was investigated for dye-sensitized solar cells (DSCs) using a series of different cobalt polypyridine redox couples, with redox potentials ranging between 0.34 and 1.20 V vs. NHE. Marcus theory was applied to explain the rate of
Teck Ming Koh et al.
ChemSusChem, 7(7), 1909-1914 (2014-05-23)
In this work, we report a new cobalt(III) complex, tris[2-(1H-pyrazol-1-yl)pyrimidine]cobalt(III) tris[bis(trifluoromethylsulfonyl)imide] (MY11), with deep redox potential (1.27 V vs NHE) as dopant for 2,2',7,7'-tetrakis-(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-OMeTAD). This dopant possesses, to the best of our knowledge, the deepest redox potential among all
Edoardo Mosconi et al.
Journal of the American Chemical Society, 134(47), 19438-19453 (2012-11-02)
We report a combined experimental and computational investigation to understand the nature of the interactions between cobalt redox mediators and TiO(2) surfaces sensitized by ruthenium and organic dyes, and their impact on the performance of the corresponding dye-sensitized solar cells
Julian Burschka et al.
Nature, 499(7458), 316-319 (2013-07-12)
Following pioneering work, solution-processable organic-inorganic hybrid perovskites-such as CH3NH3PbX3 (X = Cl, Br, I)-have attracted attention as light-harvesting materials for mesoscopic solar cells. So far, the perovskite pigment has been deposited in a single step onto mesoporous metal oxide films

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