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Merck
CN

805807

Sigma-Aldrich

FK 269 Co (III) TFSI 盐

别名:

Greatcell Solar®, bis(2,6-di(1H-pyrazol-1-yl)pyridine)cobalt(III) tri[bis(trifluoromethane)sulfonimide]

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关于此项目

经验公式（希尔记法）:
C28H18CoF18N13O12S6
分子量:
1321.82
UNSPSC代码:
12352103
PubChem化学物质编号:
329768961
NACRES:
NA.23

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方案

98%

表单

powder

mp

169.5 °C

SMILES字符串

O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.C1(N2N=CC=C2)=CC=CC(N3C=CC=N3)=N1.N4(C5=NC(N6N=CC=C6)=CC=C5)N=CC=C4.[Co+3]

InChI

1S/2C11H9N5.C2F6NO4S2.Co/c2*1-4-10(15-8-2-6-12-15)14-11(5-1)16-9-3-7-13-16;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/h2*1-9H;;/q;;-1;+3

InChI key

ZURJMCGADUHLSF-UHFFFAOYSA-N

应用

Use this cobalt complexes to increase photovoltages of liquid electrolyte cells substantially or to achieve ultrahigh performance with solid state photovoltaic devices, such as perovskite and dye-sensitized solar cells
FK269 cobalt complexes offer guaranteed performance, high reproducibility, consistent results, and are of highest purity. In comparison to triiodide-based redox electrolytes, cobalt complexes in general increase photovoltages and, particularly at lower light levels (e.g. for indoor applications), significantly increase device power output.

法律信息

Product of Greatcell Solar®
Greatcell Solar is a registered trademark of Greatcell Solar

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKBW2616V

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Sandra M Feldt et al.
Physical chemistry chemical physics : PCCP, 15(19), 7087-7097 (2013-04-05)
Regeneration and recombination kinetics was investigated for dye-sensitized solar cells (DSCs) using a series of different cobalt polypyridine redox couples, with redox potentials ranging between 0.34 and 1.20 V vs. NHE. Marcus theory was applied to explain the rate of
Teck Ming Koh et al.
ChemSusChem, 7(7), 1909-1914 (2014-05-23)
In this work, we report a new cobalt(III) complex, tris[2-(1H-pyrazol-1-yl)pyrimidine]cobalt(III) tris[bis(trifluoromethylsulfonyl)imide] (MY11), with deep redox potential (1.27 V vs NHE) as dopant for 2,2',7,7'-tetrakis-(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-OMeTAD). This dopant possesses, to the best of our knowledge, the deepest redox potential among all
Edoardo Mosconi et al.
Journal of the American Chemical Society, 134(47), 19438-19453 (2012-11-02)
We report a combined experimental and computational investigation to understand the nature of the interactions between cobalt redox mediators and TiO(2) surfaces sensitized by ruthenium and organic dyes, and their impact on the performance of the corresponding dye-sensitized solar cells
Julian Burschka et al.
Nature, 499(7458), 316-319 (2013-07-12)
Following pioneering work, solution-processable organic-inorganic hybrid perovskites-such as CH3NH3PbX3 (X = Cl, Br, I)-have attracted attention as light-harvesting materials for mesoscopic solar cells. So far, the perovskite pigment has been deposited in a single step onto mesoporous metal oxide films

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