806463
Ac-Val-OH
95%, powder
别名:
N-α-Acetyl-L-valine, N-Acyl-Valine
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关于此项目
经验公式（希尔记法）:
C7H13NO3
化学文摘社编号:
分子量:
159.18
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
EC Number:
202-537-8
MDL number:
产品名称
Ac-Val-OH,
InChI
1S/C7H13NO3/c1-4(2)6(7(10)11)8-5(3)9/h4,6H,1-3H3,(H,8,9)(H,10,11)/t6-/m0/s1
InChI key
IHYJTAOFMMMOPX-LURJTMIESA-N
SMILES string
O=C(O)[C@H](C(C)C)NC(C)=O
assay
95%
form
powder
mp
170.5 °C
application(s)
peptide synthesis
General description
Ac-Val-OH is an N-protected valine amino acid ligand. It participates in the 2,6-diolefination reaction of phenylacetic acids.
Application
Ac-Val-OH may be employed as a ligand for the meta-selective tert-alkylation reaction.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Keary M Engle et al.
Journal of the American Chemical Society, 132(40), 14137-14151 (2010-09-22)
Initial rate studies have revealed dramatic acceleration in aerobic Pd(II)-catalyzed C-H olefination reactions of phenylacetic acids when mono-N-protected amino acids are used as ligands. In light of these findings, systematic ligand tuning was undertaken, which has resulted in drastic improvements
Jie Li et al.
Journal of the American Chemical Society, 137(43), 13894-13901 (2015-09-30)
Acylated amino acid ligands enabled ruthenium(II)-catalyzed C-H functionalizations with excellent levels of meta-selectivity. The outstanding catalytic activity of the ruthenium(II) complexes derived from monoprotected amino acids (MPAA) set the stage for the first ruthenium-catalyzed meta-functionalizations with removable directing groups. Thereby
相关内容
Yu program focuses on efficient C–H bond activation for drug synthesis, using simple starting materials.
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