assay
≥95%
form
powder
reaction suitability
reagent type: catalyst
SMILES string
C1(C2=CC=C(C=CC=C3)C3=N2)=N[C@H](C4=CC=CC=C4)CO1
InChI
1S/C18H14N2O/c1-2-6-13(7-3-1)17-12-21-18(20-17)16-11-10-14-8-4-5-9-15(14)19-16/h1-11,17H,12H2/t17-/m0/s1
InChI key
OIFADUQNTPUCKK-KRWDZBQOSA-N
General description
(R)-Ph-Quinox-Pd-alkyl complex contains (R)-Ph-quinox (2-[(4R)-4,5-dihydro-4-phenyl-2-oxazolyl]quinolone) as a chiral ligand.
Application
This ligand has been proven effective in the enantioselective diamination of alkenes.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Erica L Ingalls et al.
Journal of the American Chemical Society, 135(24), 8854-8856 (2013-06-06)
An enantioselective Pd-catalyzed vicinal diamination of unactivated alkenes using N-fluorobenzenesulfonimide as both an oxidant and a source of nitrogen is reported. The use of Ph-pybox and Ph-quinox ligands afforded differentially protected vicinal diamines in good yields with high enantioselectivities. Mechanistic
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