809527
N-Cyclohexyl-2,6-bis(1-methylethyl)-Benzenamine
别名:
N-Cyclohexyl-2,6-diisoproylaniline, CyAnH
表单
crystals
mp
67-72 °C
SMILES字符串
CC(C)C1=C(N(C2CCCCC2)[H])C(C(C)C)=CC=C1
InChI
1S/C18H29N/c1-13(2)16-11-8-12-17(14(3)4)18(16)19-15-9-6-5-7-10-15/h8,11-15,19H,5-7,9-10H2,1-4H3
InChI key
YDWZEQMCJKBGTO-UHFFFAOYSA-N
一般描述
N-Cyclohexyl-2,6-bis(1-methylethyl)-benzenamine is a hindered monodentate aniline derivative.
应用
Deprotonating CyAnH to form the lithiated base LiCyAn, provides a critical reagent in the α, β-dehydrogenation of enones and other unsaturated systems under palladium catalysis, as reported by Newhouse and coworkers.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Amide a, ?-Dehydrogenation Using Allyl-Palladium Catalysis and a Hindered Monodentate Anilide.
Chen Y, et al.
Journal of the American Chemical Society, 138(4), 1166-1169 (2016)
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