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Merck
CN

809527

N-Cyclohexyl-2,6-bis(1-methylethyl)-Benzenamine

别名:

N-Cyclohexyl-2,6-diisoproylaniline, CyAnH

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关于此项目

经验公式(希尔记法):
C18H29N
化学文摘社编号:
分子量:
259.43
PubChem Substance ID:
UNSPSC Code:
12352116
Form:
crystals
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form

crystals

mp

67-72 °C

SMILES string

CC(C)C1=C(N(C2CCCCC2)[H])C(C(C)C)=CC=C1

InChI

1S/C18H29N/c1-13(2)16-11-8-12-17(14(3)4)18(16)19-15-9-6-5-7-10-15/h8,11-15,19H,5-7,9-10H2,1-4H3

InChI key

YDWZEQMCJKBGTO-UHFFFAOYSA-N

General description

N-Cyclohexyl-2,6-bis(1-methylethyl)-benzenamine is a hindered monodentate aniline derivative.

Application

Deprotonating CyAnH to form the lithiated base LiCyAn, provides a critical reagent in the α, β-dehydrogenation of enones and other unsaturated systems under palladium catalysis, as reported by Newhouse and coworkers.


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Amide a, ?-Dehydrogenation Using Allyl-Palladium Catalysis and a Hindered Monodentate Anilide.
Chen Y, et al.
Journal of the American Chemical Society, 138(4), 1166-1169 (2016)



全球贸易项目编号

货号GTIN
809527-1G04061832995847