857300
(1R)-(+)-樟脑
98%
别名:
(+)-樟脑, (1R)-1,7,7-三甲基二环[2.2.1]庚烷-2-酮
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关于此项目
经验公式（希尔记法）:
C10H16O
化学文摘社编号:
分子量:
152.23
UNSPSC Code:
12352115
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-355-2
Beilstein/REAXYS Number:
2042745
MDL number:
产品名称
(1R)-(+)-樟脑, 98%
InChI key
DSSYKIVIOFKYAU-XCBNKYQSSA-N
InChI
1S/C10H16O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7H,4-6H2,1-3H3/t7-,10+/m1/s1
SMILES string
C[C@@]1(CC2)C(C)(C)[C@H]2CC1=O
vapor density
5.24 (vs air)
vapor pressure
4 mmHg ( 70 °C)
assay
98%
form
powder
optical activity
[α]25/D +44.1°, c = 10 in ethanol
autoignition temp.
870 °F
expl. lim.
3.5 %
mp
179-181 °C (lit.)
functional group
ketone
Quality Level
Application
手性中间体和助剂。
（1R）-（+）-樟脑已被用作对称选择性气相色谱-质谱（GC-MS）分析 Achillea ligustica 精油成分的标准品。
它也可以用于合成：
它也可以用于合成：
- {N，N′-双[（1R，2R，4R）-1，7，7-三甲基双环[2.2.1]庚-2-基] -1，2-乙二胺}，C2-对称二胺
- 手性恶唑硼烷
- （-）-（1R，2R）-1，2-二羟基-3，3-二甲基降冰片烷
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 2 Inhalation
target_organs
Lungs
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 1
flash_point_f
147.2 °F - closed cup
flash_point_c
64 °C - closed cup
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Synthetic Communications, 23, 437-437 (1993)
Synthesis of C 2-symmetrical diamine based on (1R)-(+)-camphor and application to oxidative aryl coupling of naphthols.
Caselli A, et al.
Tetrahedron Asymmetry, 14(11), 1451-1454 (2003)
The Journal of Organic Chemistry, 56, 1185-1185 (1991)
Synthesis of homochiral 1, 2-diols from (-)-fenchone and (+)-camphor.
Martinez AG, et al.
Tetrahedron Asymmetry, 5(7), 1373-1376 (1994)
Asymmetric reduction of prochiral ketones using in situ generated oxazaborolidines derived from amino alcohols of (1R)-camphor as catalysts.
Santhi V and Rao JM
Tetrahedron Asymmetry, 11(17), 3553-3560 (2000)
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