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86652

四乙基高碘酸铵

Name: 四乙基高碘酸铵
Brand: ALDRICH

technical, moistened with water, ≥90% (calc. based on dry substance, RT)

别名:

N,N,N-Triethylethanaminium salt with periodic acid

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关于此项目

线性分子式:

(C₂H₅)₄N(IO₄)

化学文摘社编号:

5492-69-3

分子量:

321.15

UNSPSC Code:

12352000

NACRES:

NA.22

PubChem Substance ID:

57653063

EC Number:

226-824-2

Beilstein/REAXYS Number:

4166132

MDL number:

MFCD00043182

Assay:

≥90% (calc. based on dry substance, RT)

Form:

crystals

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属性

grade

technical

assay

≥90% (calc. based on dry substance, RT)

form

crystals

quality

moistened with water

contains

~10% water as stabilizer

reaction suitability

core: ammonium, reagent type: oxidant

mp

~170 °C (dec.)

SMILES string

[O-]I(=O)(=O)=O.CC[N+](CC)(CC)CC

InChI

1S/C8H20N.HIO4/c1-5-9(6-2,7-3)8-4;2-1(3,4)5/h5-8H2,1-4H3;(H,2,3,4,5)/q+1;/p-1

InChI key

YXYPONURGKGPDV-UHFFFAOYSA-M

说明

Application

Tetraethylammonium (meta)periodate can be used as an oxidant in the N-dealkylation of tertiary amines using Fe(III) complex as a catalyst. It can also be employed as a reagent in the intramolecular cycloaddition reactions.

Reactant for intramolecular cycloaddition reactions

Other Notes

在有机溶剂中使用的氧化剂；1,2-二醇和烯烃类化合物的氧化

pictograms

GHS02

signalword

Danger

hcodes

H228

pcodes

P210

Hazard Classifications

Flam. Sol. 1

存储类别

4.1B - Flammable solid hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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G.E. Keck

Tetrahedron Letters, 4767-4767 (1978)

Oxidative N-Dealkylation of Tertiary Amines with Tetraethylammonium Periodate Catalyzed by Metal Complexes

Bhat, Daisy and Sharma, Nidhi

Australian Journal of Chemistry, 70(3), 233-236 (2017)

A.A. Freer et al.

Journal of the Chemical Society. Perkin Transactions 1, 1001-1001 (1991)

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全球贸易项目编号

货号	GTIN
86652-50G	04061833552490
86652-10G	04061834412274