89025
硫酚铜
≥98.0% (RT)
别名:
噻吩氧化亚铜, 苯硫基铜(I), 苯硫酚 铜(I) 盐
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关于此项目
线性分子式:
C6H5SCu
化学文摘社编号:
分子量:
172.71
UNSPSC Code:
12352300
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3709171
InChI
1S/C6H6S.Cu/c7-6-4-2-1-3-5-6;/h1-5,7H;/q;+1/p-1
SMILES string
[Cu]Sc1ccccc1
InChI key
PNNJYDODNCALKD-UHFFFAOYSA-M
assay
≥98.0% (RT)
form
solid
reaction suitability
core: copper, reagent type: catalyst
mp
280 °C (dec.) (lit.)
Application
Reagents used as the source of nucleophilic phenyl sulfide for preparation of lithiumalkyl(phenylthio)cuprates and organophosphinecopper(I) phenylthiolatecomplexes
Other Notes
用于从烷基锂简易制备(苯硫基)烷基锂-铜酸盐的试剂，用于共轭加成生成 α,β-烯酮
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
P.A. Wender et al.
Tetrahedron Letters, 1245-1245 (1977)
G.H. Posner et al.
Synthesis, 662-662 (1974)
E. Piers et al.
The Journal of Organic Chemistry, 40, 2694-2694 (1975)
Majetich, G.; Song, J. et al.
The Journal of Organic Chemistry, 58, 1030-1030 (1993)
E.J. Corey et al.
Tetrahedron Letters, 4597-4597 (1978)
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