产品名称
四氟硼酸盐,
form
powder
Quality Level
reaction suitability
reagent type: catalyst
core: pyrylium
reaction type: Photocatalysis
mp
346-351 °C
SMILES string
COC(C=C1)=CC=C1C2=[O+]C(C3=CC=C(OC)C=C3)=CC(C4=CC=C(OC)C=C4)=C2.FB(F)F.[F-]
InChI
1S/C26H23O4.BF3.FH/c1-27-22-10-4-18(5-11-22)21-16-25(19-6-12-23(28-2)13-7-19)30-26(17-21)20-8-14-24(29-3)15-9-20;2-1(3)4;/h4-17H,1-3H3;;1H/q+1;;/p-1
InChI key
BYUPZXIJGVBLGP-UHFFFAOYSA-M
Application
2,4,6-三(4-甲氧基苯基)吡喃盐四氟硼酸盐可用于通过光致电子转移催化C2-对称环丁烷烯烃二聚体的立体选择性合成。该方法可用于柳叶玉兰脂素、endiandrin A和pellucidin A等木脂素的全合成。它还能催化光致电子转移（PET）引发自由基阳离子Diels-Alder反应。
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
相关内容
Nicewicz lab focuses on reactive cation radical species for selective reactions, advancing synthesis methodologies for various functional groups.
Synthesis of cyclobutane lignans via an organic single electron oxidant?electron relay system.
Riener M and Nicewicz D A
Chemical Science, 4(6), 2625-2629 (2013)
Electron?Transfer?Induced Diels?Alder Reactions of Indole and Exocyclic Dienes: Synthesis and Quantum?Chemical Studies.
Haberl U, et al.
Chemistry?A European Journal , 5(10), 2859-2865 (1999)
Christo S Sevov et al.
The Journal of organic chemistry, 73(20), 7909-7915 (2008-09-13)
Electron transfer catalysis is an effective method for the acceleration of Diels-Alder reactions between two substrates of similar electron density. The dependence of the selectivity of the Diels-Alder reaction between (R)-alpha-phellandrene and 4-methoxystyrene catalyzed by photoinduced electron transfer with tris(4-methoxyphenyl)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 900692-250MG | 04061833259290 |
| 900692-10MG | 04061833259283 |