900989
1,3,5-Phenyltriboronic acid, tris(pinacol) ester
≥97%
别名:
1,3,5-Tris(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzene
质量水平
方案
≥97%
表单
powder or crystals
mp
286-287 °C
SMILES字符串
CC1(C)OB(OC1(C)C)C2=CC(B3OC(C)(C)C(C)(C)O3)=CC(B4OC(C)(C)C(C)(C)O4)=C2
InChI
1S/C24H39B3O6/c1-19(2)20(3,4)29-25(28-19)16-13-17(26-30-21(5,6)22(7,8)31-26)15-18(14-16)27-32-23(9,10)24(11,12)33-27/h13-15H,1-12H3
InChI key
VKOLBYNBPONPAE-UHFFFAOYSA-N
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应用
1,3,5-Phenyltriboronic acid, tris(pinacol) ester can undergo Suzuki–Miyaura cross-coupling polycondensation reaction with 4,7-dibromobenzo[c][1,2,5]thiadiazole to afford conjugated polybenzothiadiazoles. It may also be used as a crosslinker for synthesizing conjugated microporous polymer (CMP) nanoparticles. This product was previously listed as BML00299.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
此项目有
Can Yang et al.
Angewandte Chemie (International ed. in English), 55(32), 9202-9206 (2016-06-16)
The search for metal-free organic photocatalysts for H2 production from water using visible light remains a key challenge. Reported herein is a molecular structural design of pure organic photocatalysts, derived from conjugated polybenzothiadiazoles, for photocatalytic H2 evolution using visible light.
Conjugated microporous polymer nanoparticles with enhanced dispersibility and water compatibility for photocatalytic applications.
Ma BC, et al.
Journal of Material Chemistry A, 3, 16064-16071 (2015)
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