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Merck
CN

901426

Propargyl methacrylate

≥98.0%, contains 200 ppm MEHQ as inhibitor

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关于此项目

经验公式(希尔记法):
C7H8O2
化学文摘社编号:
分子量:
124.14
UNSPSC Code:
12162002
MDL number:
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InChI

1S/C7H8O2/c1-4-5-9-7(8)6(2)3/h1H,2,5H2,3H3

InChI key

PZAWASVJOPLHCJ-UHFFFAOYSA-N

assay

≥98.0%

form

liquid

color

colorless to pale yellow

storage temp.

−20°C

General description

Propargyl methacrylate is a methacrylate-based monomer for use in the synthesis of alkyne-functionalized polymers and copolymers. The incorporation of alkynes allows for rapid post-polymerization modification through reactions, such as copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) or thiol-yne click reactions. These reactions are highly preferable for functionalization due their high efficiency and the ability to easily install the corresponding functionality (e.g., azides or thiols) onto the biomolecule or small molecule of interest.

pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

120.2 °F

flash_point_c

49 °C

法规信息

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Clickable and Antifouling Platform of Poly[(propargyl methacrylate)-ran-(2-methacryloyloxyethyl phosphorylcholine)] for Biosensing Applications
Wiarachai O, et al.
Langmuir, 32 (4), 1184-1194 (2016)
Self-assembling amphiphilic poly(propargyl methacrylate) grafted DNA copolymers into multi-strand helices
Meng Y F, et al.
Soft Matter, 11, 5610- 513 (2015)
Jincai Wang et al.
Journal of chromatography. A, 1628, 461481-461481 (2020-08-22)
A single-step copolymerization strategy was developed for the preparation of carbohydrate (glucose and maltose) functionalized monoliths using click reaction. Firstly, novel carbohydrate-functionalized methacrylate monomers were synthesized through Cu(I)-catalyzed 1,3-dipolar cycloaddition (alkyne-azide reaction) of terminal alkyne with azide of carbohydrate derivatives.
Postfunctionalization of poly(propargyl methacrylate) using copper catalyzed 1,3-dipolar Huisgen cycloaddition: An easy route to electro-optic materials
Scarpaci A. et al.
Journal of Polymer Science: Part A, General Papers, 47, 5652- 560 (2009)

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