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Merck
CN

902705

Diisopropyl 2-(((methylsulfonyl)oxy)imino)malonate

≥95%

别名:

Kurti doubly N-electrophilic iminomalonate

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关于此项目

经验公式(希尔记法):
C10H17NO7S
化学文摘社编号:
分子量:
295.31
UNSPSC Code:
12352101
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assay

≥95%

form

powder or crystals

Application

As demonstrated by Laszlo Kürti′s lab, ketomalonate oxime O-sulfonates act as doubly N-electrophilic linchpin reagents towards strong C-nucleophiles such as alkyl- and arylmetals (e.g., Grignard reagents). Thus, symmetrical dialkyl- as well as diarylamines may be directly prepared at low tempretatures and in the absence of transition metal catalysts. Other ketomalonate oxime O-sulfonates include 902918, 902624 and 902748.


存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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分析证书(COA)

Lot/Batch Number

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Padmanabha V Kattamuri et al.
Journal of the American Chemical Society, 139(32), 11184-11196 (2017-06-27)
Given the importance of amines in a large number of biologically active natural products, active pharmaceutical ingredients, agrochemicals, and functional materials, the development of efficient C-N bond-forming methods with wide substrate scope continues to be at the frontier of research



全球贸易项目编号

货号GTIN
902705-1G04061838694829