903183
Benzyl 4-oxo-3-(triethylsilyl)piperidine-1-carboxylate
≥95%
别名:
Garg silyl triflate precursor
assay
≥95%
form
liquid
refractive index
n/D 1.528
density
1.082 g/mL
functional group
ketone, phenyl
storage temp.
−20°C
Application
Benzyl 4-oxo-3-(triethylsilyl)piperidine-1-carboxylate is a precursor to a Garg silyl triflate which upon exposure to fluoride generates a reactive azacyclic allene for cycloaddition reactions.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
257.9 °F
flash_point_c
125.5 °C
法规信息
新产品
此项目有
Joyann S Barber et al.
Nature chemistry, 10(9), 953-960 (2018-08-01)
For over a century, the structures and reactivities of strained organic compounds have captivated the chemical community. Whereas triple-bond-containing strained intermediates have been well studied, cyclic allenes have received far less attention. Additionally, studies of cyclic allenes that bear heteroatoms
相关内容
The Garg group develops methods for the synthesis of natural products and pharmaceuticals. One key method pertains to heterocyclic arynes, such as indolynes and pyridynes, which are generated in situ from silyltriflate precursors under mild fluoride based reaction conditions.
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